m
 
(81 intermediate revisions by the same user not shown)
Line 1: Line 1:
[[file:Eutrophication image.jpg|thumb|300px|alt=image of eutrophication|<font size=3>Photo of a eutrophic lake, a result of excessive phosphorus loading.</font size>]]
+
<div style="float:right">
 +
<table class="infobox" style="border:3px; border-style:solid; border-color:#FF0000; text-align: left; width: 300px; font-size: 100%">
 +
<tr>
 +
<th><center><font size=3>'''PAGE SUMMARY'''</font size></center></th>
 +
</tr>
 +
<tr>
 +
<td>'''The following list summarizes the important points on this page'''
 +
*Phosphorus in stormwater occurs in dissolved and particulate forms. Dissolved forms typically are more than 90% bioavailable, while paarticulate forms are typically less than 25% bioavailable. For a discussion of dissolved and particulate fractions in stormwate rrunoff, see [https://stormwater.pca.state.mn.us/index.php?title=Event_mean_concentrations_of_total_and_dissolved_phosphorus_in_stormwater_runoff#Ratios_of_particulate_to_dissolved_phosphorus Ratios of particulate to dissolved phosphorus]
 +
*Typical concentrations of total phosphorus (TP) in stormwater vary with land use, ranging from about 0.19 mg/L from open space areas to about 0.32 mg/L for residential areas. TP export from urban land uses are typically 1-3 lb/ac/yr.
 +
*Stormwater management should utilize a [https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#Stormwater_management_for_phosphorus treatment train approach] and focus on dissolved phosphorus in areas where contributions of dissolved phosphorus are significant.
 +
*Infiltration, pollution prevention, and use of amendments are effective for dissolved phosphorus
 +
*Erosion control, filtration, and sedimentation practices are effective for particulate phosphorus but less effective for dissolved phosphorus
 +
</td>
 +
</tr>
 +
</table>
 +
</div>
 +
 
 +
[[File:General information page image.png|left|100px|alt=image]]
 +
[[file:Eutrophication image.jpg|thumb|left|300px|alt=image of eutrophication|<font size=3>Photo of a eutrophic lake, a result of excessive phosphorus loading.</font size>]]
  
 
[https://water.usgs.gov/edu/phosphorus.html The United States Geological Survey] states: "Phosphorus is a common constituent of agricultural fertilizers, manure, [urban runoff], and organic wastes in sewage and industrial effluent. It is an essential element for plant life, but when there is too much of it in water, it can speed up [https://stormwater.pca.state.mn.us/index.php?title=Glossary#E eutrophication] (a reduction in dissolved oxygen in water bodies caused by an increase of mineral and organic nutrients) of rivers and lakes." Phosphorus in stormwater runoff can generally be divided into the fraction associated with sediment, called particulate phosphorus, and the fraction dissolved in water, called dissolved or soluble phosphorus. Total phosphorus is the sum of particulate and dissolved phosphorus and includes the total amount of phosphorus in both organic and inorganic forms.  Orthophosphate measures phosphorus that is most immediately biologically available.  Most of the soluble phosphorus in stormwater is usually present in the orthophosphate form.
 
[https://water.usgs.gov/edu/phosphorus.html The United States Geological Survey] states: "Phosphorus is a common constituent of agricultural fertilizers, manure, [urban runoff], and organic wastes in sewage and industrial effluent. It is an essential element for plant life, but when there is too much of it in water, it can speed up [https://stormwater.pca.state.mn.us/index.php?title=Glossary#E eutrophication] (a reduction in dissolved oxygen in water bodies caused by an increase of mineral and organic nutrients) of rivers and lakes." Phosphorus in stormwater runoff can generally be divided into the fraction associated with sediment, called particulate phosphorus, and the fraction dissolved in water, called dissolved or soluble phosphorus. Total phosphorus is the sum of particulate and dissolved phosphorus and includes the total amount of phosphorus in both organic and inorganic forms.  Orthophosphate measures phosphorus that is most immediately biologically available.  Most of the soluble phosphorus in stormwater is usually present in the orthophosphate form.
  
This article provides information on phosphorus in urban stormwater, including a discussion of sources of phosphorus and management strategies for minimizing phosphorus loading from urban stormwater runoff to surface water. For more information on phosphorus in water, click on these links: [https://www.water-research.net/index.php/phosphate-in-water], [https://www.pca.state.mn.us/sites/default/files/wq-iw3-12.pdf], [http://www.water.ncsu.edu/watershedss/info/phos.html], [http://bcn.boulder.co.us/basin/data/NEW/info/TP.html], [https://www.nrcs.usda.gov/wps/portal/nrcs/detail/national/technical/nra/rca/?cid=nrcs143_014203].
+
This article provides information on phosphorus in urban stormwater, including a discussion of sources of phosphorus and management strategies for minimizing phosphorus loading from urban stormwater runoff to surface water. For more information on phosphorus in water, click on these links: [https://www.water-research.net/index.php/phosphate-in-water], [http://bcn.boulder.co.us/basin/data/NEW/info/TP.html], [https://www.pca.state.mn.us/pollutants-and-contaminants/phosphorus], [https://www.epa.gov/national-aquatic-resource-surveys/indicators-phosphorus], [https://www.des.nh.gov/sites/g/files/ehbemt341/files/documents/2020-01/bb-20.pdf].
 +
 
 +
{{alert|Blue alert boxes are used throughout this page to identify best practices for minimizing dissolved phosphorus. Dissolved phosphorus has the greatest impact on receiving waters and minimizing or treating for dissolved phosphorus in runoff should be a priority for protecting receiving waters.|alert-info}}
 +
 
 +
==Forms of phosphorus found in stormwater and natural waters==
 +
[[File:Phosphorus speciation.png|500px|thumb|alt=image of phosphorus speciation|<font size=3>Schematic showing analysis for different forms of phosphorus in water. Filtered phosphorus is considered to represent dissolved phosphorus, while unfiltered phosphorus represents all phosphorus. Particulate phosphorus is the difference between filtered and unfiltered.</font size>]]
 +
 
 +
Phosphorus in water is often classified as dissolved (soluble) or particulate (attached to or a component of particulate matter) phosphorus. This nomenclature is somewhat ambiguous, however, as dissolved phosphorus consists of multiple forms of phosphorus, including phosphorus attached to other materials. Dissolved phosphorus is typically identified as phosphorus passing through a 0.45 micron filter. It is this dissolved fraction that is considered to be most <span title="the proportion of a nutrient that is digested, absorbed and metabolized by an organism through normal pathways."> '''bioavailable'''</span> and most difficult to treat. Understanding phosphorus behavior is further complicated by environmental conditions, particularly <span title="a type of chemical reaction that involves a transfer of electrons between two species. An oxidation-reduction reaction is any chemical reaction in which the oxidation number of a molecule, atom, or ion changes by gaining or losing an electron"> '''oxidation-reduction'''</span> (redox) conditions, since a portion of particulate phosphorus will release phosphorus under <span title="an aquatic environment lacking oxygen"> '''anoxic'''</span> (reducing) conditions.
 +
 
 +
Other terms encountered or forms of phosphorus discussed in the literature include the following.
 +
*Total phosphorus (TP) is a measure of all the forms of phosphorus, dissolved or particulate, that are found in a sample.
 +
*Inorganic phosphate is phosphate not associated with organic material. Types of inorganic phosphate include orthophosphate (PO<sub>4</sub><sup>-2</sup>) and polyphosphates.
 +
*Organic phosphate is phosphate that is bound to plant or animal tissue.
 +
*Phosphate or orthophosphate refers to the phosphate molecule by itself.
 +
*Reactive phosphorus is the phosphorus associated with the test for orthophosphate. It consists mostly of orthophosphate but includes a small fraction of other forms.
 +
*Soluble reactive phosphorus is a measure of orthophosphate, the filterable (soluble, inorganic) fraction of phosphorus, the form directly taken up by plant cells.
 +
*Bioavailable phosphorus is the sum of immediately available phosphorus, which can be transformed into an available form by naturally occurring processes.
 +
 
 +
The following links provide discussion of phosphorus in stormwater.
 +
*[[Event mean concentrations of total and dissolved phosphorus in stormwater runoff]]
 +
*[https://stormwater.pca.state.mn.us/index.php?title=Event_mean_concentrations_of_total_and_dissolved_phosphorus_in_stormwater_runoff#Ratios_of_particulate_to_dissolved_phosphorus Ratios of particulate to dissolved phosphorus]
 +
*[[Dissolved phosphorus in stormwater runoff - sources and management strategies]]
 +
*[https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#Source_and_concentrations_of_phosphorus_in_urban_stormwater Source and concentrations of phosphorus in urban stormwater]
 +
 
 +
References for phosphorus forms and testing includes the following.
 +
*[https://archive.epa.gov/water/archive/web/html/vms56.html US EPA]
 +
*[https://www.epa.gov/sites/default/files/2015-10/documents/status-nutrients-lake-erie-basin-2010-42pp.pdf Lake Erie Algae]
 +
*[https://www.water-research.net/index.php/phosphate-in-water Water Research Center]
 +
*[https://bcn.boulder.co.us/basin/data/NEW/info/TP.html Boulder, CO]
 +
 
 +
==Bioavailability of different forms of phosphorus==
 +
An important consideration in treating stormwater runoff is the form of the phosphorus. As stated above, dissolved phosphorus is considered to be more bioavailable than particulate forms of phosphorus. Below is a summary of some studies on bioavailability of phosphorus.
 +
*About 95% of dissolved phosphorus transported to Lake Erie is bioavailable to algae, while only about 30% of the particulate phosphorus attached to eroded sediment is bioavailable (Lake Erie Algae).
 +
*[https://www.sciencedirect.com/science/article/pii/S0043135406000352 Ellison and Brett] (2006) found on average only 20% of the particulate phosphorus transported in runoff from urban settings was biologically available.
 +
*[https://www.tandfonline.com/doi/full/10.1080/00288330.2013.792851 Abell and Hamilton] (2012) found that about 25% of particulate phosphorus in a stream dominated by stormwater runoff was bioavailable.
 +
*[https://onlinelibrary.wiley.com/doi/full/10.1111/1752-1688.12366 Prestigiacomo et al.] found 10-20% of particulate phosphorus was bioavailable, compared to more than 90% of dissolved phosphorus being bioavailable. Bioavailable phosphorus in the particulate fraction increased somewhat with time after sampling, but never exceeded 30%.
 +
*[https://www.semanticscholar.org/paper/Contribution-of-particulate-phosphorus-to-runoff-Uusitalo-Turtola/54189c9219e05e1b9c66b35a5af7799dc4d4e9a8 Uusitalo et al.] (2003) found 6-10% of particulate phosphorus was bioavailable, but that 34-56% was redox-sensitive, meaning it could become bioavailable under anoxic (reducing) conditions. Other papers corroborate these findings, indicating that a significant portion of particulate phosphorus can become bioavailable under anoxic conditions ([https://www.ncbi.nlm.nih.gov/pubmed/21235180], [https://www.researchgate.net/profile/Colin_Reynolds/publication/229477072_Phosphorus_recycling_in_lakes_Evidence_from_large_limnetic_enclosures_for_the_importance_of_shallow_sediments/links/5a1fdef2458515a4c3d4e69b/Phosphorus-recycling-in-lakes-Evidence-from-large-limnetic-enclosures-for-the-importance-of-shallow-sediments.pdf], [https://www.biogeosciences.net/14/3585/2017/bg-14-3585-2017.pdf], [https://link.springer.com/article/10.1007/BF00024902])
  
 
==Source and concentrations of phosphorus in urban stormwater==
 
==Source and concentrations of phosphorus in urban stormwater==
 
Sources of phosphorus in urban runoff include plant and leaf litter, soil particles, pet waste, road salt, fertilizer, and atmospheric deposition of particles. Lawns and roads account for the greatest loading. For example, [https://www.researchgate.net/profile/William_Selbig/publication/252504344_Sources_of_Phosphorus_in_Stormwater_and_Street_Dirt_From_Two_Urban_Residential_Basins_in_Madison_Wisconsin_1994-95/links/567815c408aebcdda0ebbbab/Sources-of-Phosphorus-in-Stormwater-and-Street-Dirt-From-Two-Urban-Residential-Basins-in-Madison-Wisconsin-1994-95.pdf Waschbusch et. al] (1999) found that lawns and roads contributed about 80 percent of total and dissolved phosphorus loading. Land use affects the contribution from different sources, with lawns and leaf litter being more important in residential areas and roads being more important in commercial and industrial areas. Atmospheric sources of particles may derive from outside of the river basin ([https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#References Hopke et al. 1980]; [https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#References Tipping et al., 2014]).
 
Sources of phosphorus in urban runoff include plant and leaf litter, soil particles, pet waste, road salt, fertilizer, and atmospheric deposition of particles. Lawns and roads account for the greatest loading. For example, [https://www.researchgate.net/profile/William_Selbig/publication/252504344_Sources_of_Phosphorus_in_Stormwater_and_Street_Dirt_From_Two_Urban_Residential_Basins_in_Madison_Wisconsin_1994-95/links/567815c408aebcdda0ebbbab/Sources-of-Phosphorus-in-Stormwater-and-Street-Dirt-From-Two-Urban-Residential-Basins-in-Madison-Wisconsin-1994-95.pdf Waschbusch et. al] (1999) found that lawns and roads contributed about 80 percent of total and dissolved phosphorus loading. Land use affects the contribution from different sources, with lawns and leaf litter being more important in residential areas and roads being more important in commercial and industrial areas. Atmospheric sources of particles may derive from outside of the river basin ([https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#References Hopke et al. 1980]; [https://stormwater.pca.state.mn.us/index.php?title=Phosphorus_in_stormwater#References Tipping et al., 2014]).
  
Dissolved phosphorus typically accounts for about 45 percent of total phosphorus, but this fraction varies with the source of phosphorus.  The dissolved fraction may be as high as 50 percent when the source is plant litter and lawns, while the dissolved fraction may be as low as 25 percent when the source is predominantly roads ([https://www.researchgate.net/profile/William_Selbig/publication/252504344_Sources_of_Phosphorus_in_Stormwater_and_Street_Dirt_From_Two_Urban_Residential_Basins_in_Madison_Wisconsin_1994-95/links/567815c408aebcdda0ebbbab/Sources-of-Phosphorus-in-Stormwater-and-Street-Dirt-From-Two-Urban-Residential-Basins-in-Madison-Wisconsin-1994-95.pdf Waschbusch et. al, 1999]). For more information on phosphorus in urban stormwater, see the section on [https://stormwater.pca.state.mn.us/index.php?title=Street_sweeping_for_trees#Contribution_of_tree_leaves.2C_seeds.2C_and_flowers_to_phosphorus_in_urban_runoff contribution of tree leaves, seeds, and flowers to phosphorus in urban runoff].
+
The fraction of total phosphorus in dissolved form varies with the source of phosphorus, which in turn varies with season and land use.  The dissolved fraction may exceed 50 percent when the source is plant litter, fertilizer, and animal waste, while the dissolved fraction may be as low as 25 percent when the source is predominantly sediment ([https://www.researchgate.net/profile/William_Selbig/publication/252504344_Sources_of_Phosphorus_in_Stormwater_and_Street_Dirt_From_Two_Urban_Residential_Basins_in_Madison_Wisconsin_1994-95/links/567815c408aebcdda0ebbbab/Sources-of-Phosphorus-in-Stormwater-and-Street-Dirt-From-Two-Urban-Residential-Basins-in-Madison-Wisconsin-1994-95.pdf Waschbusch et. al, 1999]). For more information on phosphorus in urban stormwater, see the section on [https://stormwater.pca.state.mn.us/index.php?title=Street_sweeping_for_trees#Contribution_of_tree_leaves.2C_seeds.2C_and_flowers_to_phosphorus_in_urban_runoff contribution of tree leaves, seeds, and flowers to phosphorus in urban runoff]. For a detailed discussion of dissolved and particulate fractions in runoff, [https://stormwater.pca.state.mn.us/index.php?title=Event_mean_concentrations_of_total_and_dissolved_phosphorus_in_stormwater_runoff#Ratios_of_particulate_to_dissolved_phosphorus link here].
  
Concentrations of phosphorus in urban stormwater runoff are highly variable. Concentrations are similar across different land uses. Data below are from the [http://www.bmpdatabase.org/ International Stormwater Database], Version 3 (2008). For additional information, [http://www.dtic.mil/dtic/tr/fulltext/u2/a430436.pdf Lin] (2004) provides a good review of published event mean concentration data.
+
Concentrations of phosphorus in urban stormwater runoff are highly variable. The following table provides data on event mean concentrations of total phosphorus in stormwater, by land use. For more information on phosphorus concentrations in stormwater runoff, see [[Event mean concentrations of total and dissolved phosphorus in stormwater runoff]].
  
{| class="wikitable"
+
{{:Event mean concentrations for total phosphorus}}
|-
 
! Land use !! Median (mg/L) !! Minimum (mg/L) !! Maximum (mg/L) !! Number of observations
 
|-
 
| Commercial || 0.2 || < 0.01 || 4.27 || 56
 
|-
 
| Industrial || 0.23 || < 0.02 || 7.9 || 57
 
|-
 
| Residential || 0.26 || < 0.01 || 19.9 || 148
 
|-
 
| Open space || 0.13 || < 0.01 || 0.76 || 15
 
|-
 
| Native prairie || 0.3 || 0.1 || 0.5 ||
 
|}
 
  
Total phosphorus (TP) export varies with the amount of runoff and is calculated by multiplying the TP concentration by the volume of runoff. The [https://stormwater.pca.state.mn.us/index.php?title=The_Simple_Method_for_estimating_phosphorus_export Simple Method] can be used to estimate TP loading as a function of different land uses. Export coefficients are presented in the literature for different land uses. The data are highly variable as a result of the differences in impervious surface, even within specific land uses. Typical annual TP export coefficients are shown below (data adapted from studies cited in [http://www.dtic.mil/dtic/tr/fulltext/u2/a430436.pdf Lin] (2004) and [https://archive.org/details/exportcoefficien00jeje_0/page/n0 Jeje] (2006)).
+
Total phosphorus (TP) export varies with the amount of runoff and is calculated by multiplying the TP concentration by the volume of runoff. The [https://stormwater.pca.state.mn.us/index.php?title=The_Simple_Method_for_estimating_phosphorus_export Simple Method] can be used to estimate TP loading as a function of different land uses. Export coefficients are presented in the literature for different land uses. The data are highly variable as a result of the differences in impervious surface, even within specific land uses. Typical annual TP export coefficients are shown below (data adapted from studies cited in [https://apps.dtic.mil/sti/pdfs/ADA430436.pdf Lin] (2004) and [https://archive.org/details/exportcoefficien00jeje_0/page/n0 Jeje] (2006)).
  
 
{| class="wikitable"
 
{| class="wikitable"
Line 51: Line 92:
 
| Highways ||  || 3.1
 
| Highways ||  || 3.1
 
|}
 
|}
 
==Meeting TP water quality targets==
 
Information on this page can be used to help meet water quality targets. Water quality targets are established for various purposes including meeting Clean Water Act (CWA) requirements, meeting local water quality goals or requirements, and meeting non-regulatory targets. CWA requirements include antidegradation, TMDL limits, and NPDES permit requirements. Each of these are described below.
 
 
{{alert|Note that information presented in the Stormwater Manual can be used to meet NPDES permit requirements. This includes information on all BMPs discussed in the Manual unless otherwise noted. Check with MPCA's Stormwater Program for applicability of information not contained in the Manual, including BMPs and BMP credits.|alert-info}}
 
 
===Antidegradation===
 
Water quality standards include an antidegradation policy and implementation method. The water quality standards regulation requires States and Tribes to establish a three-tiered antidegradation program to protect existing water quality and water uses in receiving waters (see [http://water.epa.gov/scitech/swguidance/standards/adeg.cfm]).
 
 
Compliance with [http://stormwater.pca.state.mn.us/index.php/MS4_PART_III.STORMWATER_POLLUTION_PREVENTION_PROGRAM_%28SWPPP%29#5._Post-Construction_Stormwater_Management Minimum Control Measure (MCM) 5] of the MS4 permit constitutes compliance with antidegradation requirements. The permit requires no net increase in discharges of volume, total phosphorus (TP) and total suspended solids (TSS) for new development, while a reduction in these are required for redevelopment projects covered under the permit.  Practices that [https://stormwater.pca.state.mn.us/index.php?title=BMPs_for_stormwater_infiltration infiltrate] or [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_and_rainwater_harvest_and_use/reuse capture and reuse stormwater runoff] are typically used to meet these permit requirements because they help meet the volume requirements.
 
 
===Total Maximum Daily Loads (TMDLs)===
 
The 2016 impaired water list includes 358 lakes or reservoirs and 44 river or stream stretches impaired for nutrrient/eutrophication biological indicators. Phosphorus is likely to be the surrogate pollutant for most of these impairments. Other impairments, such as those for dissolved oxygen, may also be associated with excessive TP loads. Click [https://www.pca.state.mn.us/water/minnesotas-impaired-waters-list here] to link to MPCA's impaired waters website.
 
 
The MS4 permit requires permittees to demonstrate progress toward meeting applicable Wasteload Allocations in U.S. EPA-approved TMDLs. General information on meeting TMDL requirements in NPDES permits is found [http://stormwater.pca.state.mn.us/index.php/MS4_PART_III.STORMWATER_POLLUTION_PREVENTION_PROGRAM_%28SWPPP%29#E._Discharges_to_Impaired_Waters_with_a_USEPA-Approved_TMDL_that_Includes_an_Applicable_WLA here], while reporting requirements are found [http://stormwater.pca.state.mn.us/index.php/Guidance_for_completing_the_TMDL_reporting_form#TMDL_requirements_in_stormwater_permits here]. Below is additional information that may be useful.
 
*[http://stormwater.pca.state.mn.us/index.php/Forms_and_guidance_for_TMDLs Forms and guidance for TMDLs]: includes information on completing the TMDL Annual Report form and other guidance documents.
 
*Information on modeling, including [[Available stormwater models and selecting a model]] and [[Detailed information on specific models]].
 
*[[Information on pollutant removal by BMPs]]. Pollutant removal information is limited to structural BMPs. Each BMP included in the manual also has a [https://stormwater.pca.state.mn.us/index.php?title=Category:Calculating_credits section on credits], which provides useful information for determining pollutant removal for TP for that BMP.
 
 
Permittees with required reductions in TP loading should consider implementing a [[Using the treatment train approach to BMP selection|treatment train approach]], which is discussed in greater detail below.
 
  
 
==Stormwater management for phosphorus==
 
==Stormwater management for phosphorus==
 
[[File:Watershed scale stormwater treatment train.PNG|thumb|300px|alt=photo illustrating a watershed scale treatment train approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff.|<font size=3>Watershed scale stormwater management approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff. The BMP sequence starts with pollution prevention and progresses through source control, on-site treatment, and regional treatment before the runoff water is discharged to a receiving water. On-site and regional practices treat stormwater runoff and can be incorporated into a stormwater treatment train.</font size>]]
 
[[File:Watershed scale stormwater treatment train.PNG|thumb|300px|alt=photo illustrating a watershed scale treatment train approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff.|<font size=3>Watershed scale stormwater management approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff. The BMP sequence starts with pollution prevention and progresses through source control, on-site treatment, and regional treatment before the runoff water is discharged to a receiving water. On-site and regional practices treat stormwater runoff and can be incorporated into a stormwater treatment train.</font size>]]
  
Management of urban stormwater to control or reduce TP concentrations and loading should focus on identifying the most important sources and employing specific practices to address those sources. If significant reductions in TP loading are required or desired, a [http://stormwater.pca.state.mn.us/index.php/Using_the_treatment_train_approach_to_BMP_selection treatment train approach] should be utilized. The treatment train approach for TP focuses on implementing the following hierarchy of practices:
+
Management of urban stormwater to control or reduce TP concentrations and loading should focus on identifying the most important sources and employing specific practices to address those sources. If significant reductions in TP loading are required or desired, a <span title="multiple BMPs that work together to remove pollutants utilizing combinations of hydraulic, physical, biological, and chemical methods"> [https://stormwater.pca.state.mn.us/index.php?title=Using_the_treatment_train_approach_to_BMP_selection '''treatment train''']</span> approach should be utilized. The treatment train approach for TP focuses on implementing the following hierarchy of practices:
*pollution prevention and source control
+
*<span title="any practice that reduces, eliminates, or prevents pollution at its source"> '''pollution prevention'''</span> and source control
*pre-treatment for structural BMPs
+
*<span title="Pretreatment reduces maintenance and prolongs the lifespan of structural stormwater BMPs by removing trash, debris, organic materials, coarse sediments, and associated pollutants prior to entering structural stormwater BMPs. Implementing pretreatment devices also improves aesthetics by capturing debris in focused or hidden areas. Pretreatment practices include settling devices, screens, and pretreatment vegetated filter strips."> [https://stormwater.pca.state.mn.us/index.php?title=Pretreatment '''pretreatment''']</span> for <span title="a stationary and permanent BMP that is designed, constructed and operated to prevent or reduce the discharge of pollutants in stormwater"> '''structural stormwater BMPs'''</span>
*infiltration
+
*<span title="Infiltration Best Management Practices (BMPs) treat urban stormwater runoff as it flows through a filtering medium and into underlying soil, where it may eventually percolate into groundwater. The filtering media is typically coarse-textured and may contain organic material, as in the case of bioinfiltration BMPs."> [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_infiltration_Best_Management_Practices '''infiltration''']</span>
*settling
+
*<span title="Sedimentation is the process by which solids are removed from the water column by settling. Sedimentation practices include dry ponds, wet ponds, wet vaults, and other devices."> [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_sedimentation_Best_Management_Practices '''sedimentation''']</span>
*filtration
+
*<span title="Filtration Best Management Practices (BMPs) treat urban stormwater runoff as it flows through a filtering medium, such as sand or an organic material. They are generally used on small drainage areas (5 acres or less) and are primarily designed for pollutant removal. They are effective at removing total suspended solids (TSS), particulate phosphorus, metals, and most organics. They are less effective for soluble pollutants such as dissolved phosphorus, chloride, and nitrate."> [https://stormwater.pca.state.mn.us/index.php?title=Filtration '''filtration''']</span>
  
 
===Construction stormwater===
 
===Construction stormwater===
Data on TP loading from construction stormwater sites is limited. TSS concentrations in runoff from construction sites typically greatly exceed concentrations from other urban land uses and generally exceed 1000 milligrams per liter. Sediment export from construction sites typically ranges from 2000 to 16000 pounds per acre per year (Line et al., 2009; Line et al., 2011; Wolman and Schick, 1967). However, [https://fortress.wa.gov/ecy/publications/documents/0703027.pdf one study in Washington state] showed TP concentrations ranged from 0.01 to 0.16 milligrams per liter in runoff from construction sites, with a median of 0.095 milligrams per liter. These are relatively low concentrations considering the amount of sediment leaving construction sites. Other potential sources of phosphorus on a construction site result from land treatment practices  
+
Data on TP loading from construction stormwater sites is limited. TSS concentrations in runoff from construction sites typically greatly exceed concentrations from other urban land uses and generally exceed 1000 milligrams per liter. Sediment export from construction sites typically ranges from 2000 to 16000 pounds per acre per year (Line et al., 2009; Line et al., 2011; Wolman and Schick, 1967). However, [https://fortress.wa.gov/ecy/publications/documents/0703027.pdf one study in Washington state] showed TP concentrations ranged from 0.01 to 0.16 milligrams per liter in runoff from construction sites, with a median of 0.095 milligrams per liter. These are relatively low concentrations considering the amount of sediment leaving construction sites. Other potential sources of phosphorus on a construction site result from land treatment practices employed by the construction site personnel, such as fertilizers, <span title="Tackifiers and soil stabilizers are hydraulically applied chemicals derived from natural and synthetic sources used to promote adhesion among soil particles or mulch materials"> '''[https://stormwater.pca.state.mn.us/index.php?title=Erosion_prevention_practices_-_tackifiers_and_soil_stabilizers tackifier]'''</span>, <span title=" a planting process that uses a slurry of seed and mulch. It is often used as an erosion control technique on construction sites, as an alternative to the traditional process of broadcasting or sowing dry seed."> '''[https://stormwater.pca.state.mn.us/index.php?title=Erosion_prevention_practices_-_temporary_seeding_and_stabilization hydroseed]'''</span>, wood mulch, or other types of applications.  These products could be evaluated for their phosphorus content. <span title="practices designed to prevent or minimize erosion> [https://stormwater.pca.state.mn.us/index.php?title=Erosion_prevention_practices '''Erosion protection''']</span> and <span title="practices designed to prevent or minimize loss of eroded soil at a site"> [https://stormwater.pca.state.mn.us/index.php?title=Sediment_control_practices '''sediment control''']</span> practices [https://stormwater.pca.state.mn.us/index.php?title=Construction_stormwater_program#Best_Management_Practices described in this manual] should be employed at construction sites.
employed by the construction site personnel, such as fertilizers, tackifiers, hydroseed, wood mulch, or other types of applications.  These products could be evaluated for their phosphorus content. Erosion and sediment control practices [https://stormwater.pca.state.mn.us/index.php?title=Construction_stormwater_program#Best_Management_Practices described in this manual] should be employed at construction sites.
+
 
 +
{{alert|At most construction sites, most phosphorus will be in particulate form, which is typically easier to treat and less bioavailable than dissolved forms. To minimize dissolved phosphorus export, minimze the use of fertilizers, use slow release fertilizers, and avoid organic materials, such as compost, than can release soluble phosphorus.|alert-info}}
  
 
===Pollution prevention and source control===
 
===Pollution prevention and source control===
 
These practices reduce the amount of TP generated or remove TP prior to it being entrained in runoff. These are summarized below for residential, municipal, and industrial sources.
 
These practices reduce the amount of TP generated or remove TP prior to it being entrained in runoff. These are summarized below for residential, municipal, and industrial sources.
 +
 +
{{alert|Pollution prevention practices are among the most effective methods for minimizing dissolved phosphorus loads since these practices typically address important sources of dissolved phosphorus.|alert-info}}
  
 
====Prevention practices for residential areas====
 
====Prevention practices for residential areas====
Line 105: Line 129:
  
 
====Street sweeping====
 
====Street sweeping====
 +
{{alert|The MPCA is currently working with the University of Minnesota to develop a street sweeping credit. [[Future updates|Link to our Future Updates page for more information]].|alert-info}}
 +
 
Street sweeping can be an effective practice for reducing sediment loading to surface water, which in turn reduces loading of particulate phosphorus. This Manual currently has a short page describing [http://stormwater.pca.state.mn.us/index.php/Street_sweeping_for_trees street sweeping practices] as they relate to phosphorus management. The page includes a link to a [http://larrybakerlab.cfans.umn.edu/research-themes/source-reduction-improve-urban-stormwater-quality calculator developed at the University of Minnesota]. The calculator estimates reductions in wet and dry solids as a function of different management practices.
 
Street sweeping can be an effective practice for reducing sediment loading to surface water, which in turn reduces loading of particulate phosphorus. This Manual currently has a short page describing [http://stormwater.pca.state.mn.us/index.php/Street_sweeping_for_trees street sweeping practices] as they relate to phosphorus management. The page includes a link to a [http://larrybakerlab.cfans.umn.edu/research-themes/source-reduction-improve-urban-stormwater-quality calculator developed at the University of Minnesota]. The calculator estimates reductions in wet and dry solids as a function of different management practices.
  
Line 111: Line 137:
 
*[https://www.worldsweeper.com/Street/Studies/CWPStudy/CBStreetSweeping.pdf Law et al.] (2008) found for a given set of assumptions and sweeping frequencies, it is expected that the range in pollutant removal rates from street sweeping for total solids was 3 to 8 percent, with the lower end representing monthly street sweeping by a mechanical street sweeper and the upper end the pollutant removal efficiencies using regenerative air/vacuum street sweeper at weekly frequencies.
 
*[https://www.worldsweeper.com/Street/Studies/CWPStudy/CBStreetSweeping.pdf Law et al.] (2008) found for a given set of assumptions and sweeping frequencies, it is expected that the range in pollutant removal rates from street sweeping for total solids was 3 to 8 percent, with the lower end representing monthly street sweeping by a mechanical street sweeper and the upper end the pollutant removal efficiencies using regenerative air/vacuum street sweeper at weekly frequencies.
 
*[http://pubs.usgs.gov/sir/2007/5156/#a Sutherland] (2011) provides a comprehensive summary of street sweeping, including information on effectiveness of different sweepers and factors affecting the performance of street sweeping.
 
*[http://pubs.usgs.gov/sir/2007/5156/#a Sutherland] (2011) provides a comprehensive summary of street sweeping, including information on effectiveness of different sweepers and factors affecting the performance of street sweeping.
 +
 +
{{alert|Properly timed street sweeping (e.g. during fall leaf drop) can be a very effective method of reducing dissolved phosphorus loads since leaves are an important source of dissolved phosphorus|alert-info}}
  
 
===Pretreatment===
 
===Pretreatment===
Pretreatment is needed to protect infiltration and filtration BMPs from the build-up of trash, gross solids, and particulate matter. When the velocity of stormwater decreases, sediment and solids drop out. If pretreatment is not provided, this process will occur in the infiltration or filtration cell, resulting in long-term clogging and poor aesthetics. Therefore, pretreatment is a required part of the design for infiltration and filtration BMPs. There are three typical methods for pretreatment: vegetated filter strips (VFS), forebays, and vegetated swales. These are discussed in the section on [[Pretreatment|pretreatment]].
+
Pretreatment is needed to protect infiltration and filtration BMPs from the build-up of trash, gross solids, and particulate matter. When the velocity of stormwater decreases, sediment and solids drop out. If pretreatment is not provided, this process will occur in the infiltration or filtration cell, resulting in long-term clogging and poor aesthetics. Therefore, pretreatment is a required part of the design for infiltration and filtration BMPs. There are three typical methods for pretreatment: <span title="Pretreatment vegetated filter strips are designed to provide sedimentation and screening (by vegetation) to treat stormwater runoff prior to entering a structural stormwater BMP. Pretreatment vegetated filter strips are especially effective at capturing excess sediment in stormwater runoff by settling solids. Pretreatment vegetated filter strips provide limited (due to size) volume reduction, peak flow reduction, infiltration, and biological treatment. Stormwater management processes not provided in pretreatment vegetated filter strips include filtration and sorption."> [https://stormwater.pca.state.mn.us/index.php?title=Overview_for_pretreatment_vegetated_filter_strips '''Vegetated filter strips''']</span> (VFS), <span title="an artificial pool of water in front of a larger body of water. The larger body of water may be natural or man-made. Forebays have a number of functions. They may be used upstream of reservoirs to trap sediment and debris (sometimes called a sediment forebay) in order to keep the reservoir clean."> '''[https://stormwater.pca.state.mn.us/index.php?title=Pretreatment_-_Screening_and_straining_devices,_including_forebays forebays]'''</span>, and <span title="A shallow channel with sloping sides that is stabilized with vegetation to serve as a filtration device to capture sediments and transport water."> '''[https://stormwater.pca.state.mn.us/index.php?title=Dry_swale_(Grass_swale) vegetated swales]'''</span>. These are discussed in the section on [[Pretreatment|pretreatment]].
 +
 
 +
{{alert|Pretreatment is generally ineffective for treating dissolved phosphorus, although devices that effectively screen coarse organic debris can be effective if cleaned during times when coarse organic loads are heavy (e.g. during leaf drop). Some pretreatment practices can be modified with an amendment to enhance removal of dissolved phosphorus.|alert-info}}
  
 
===Infiltration===
 
===Infiltration===
Infiltration practices are structural Best Management Practices (BMPs) designed to capture stormwater runoff and allow the captured water to infiltrate into soils underlying the BMP. Infiltration BMPs are designed to capture a particular amount of runoff. For example, the construction stormwater permit requires that post-construction BMPs capture the first inch of runoff from new impervious surfaces, assuming there are no constraints to infiltration. BMPs designed to meet the construction stormwater permit are required to infiltrate captured water within 48 hours, with 24 hours recommended when discharges are to a trout stream.
+
Infiltration practices are structural Best Management Practices (BMPs) designed to capture stormwater runoff and allow the captured water to infiltrate into soils underlying the BMP. Infiltration BMPs are designed to capture a particular amount of runoff. For example, the [https://stormwater.pca.state.mn.us/index.php?title=Construction_stormwater_program construction stormwater permit] requires that post-construction BMPs capture the first inch of runoff from new impervious surfaces, assuming there are no constraints to infiltration. BMPs designed to meet the construction stormwater permit are required to infiltrate captured water within 48 hours, with 24 hours recommended when discharges are to a trout stream.
  
TP removal is assumed to be 100 percent for all water that infiltrates.  Any water bypassing the BMP does not receive treatment.  Examples of infiltration BMPs, with links to appropriate sections in the Manual, include the following.
+
TP removal is assumed to be 100 percent for all water that infiltrates.  Any water <span title="Stormwater runoff in excess of the design flow, which is diverted around a stormwater structure"> '''bypassing'''</span> the BMP does not receive treatment.  Examples of infiltration BMPs, with links to appropriate sections in the Manual, include the following.
 
*[[Infiltration]] (infiltration basin, infiltration trench, dry well, underground infiltration)
 
*[[Infiltration]] (infiltration basin, infiltration trench, dry well, underground infiltration)
 
*[[Bioretention|Bioinfiltration]] (rain garden or bioretention with no underdrain)
 
*[[Bioretention|Bioinfiltration]] (rain garden or bioretention with no underdrain)
 
*[[Permeable pavement]]
 
*[[Permeable pavement]]
 
*[[Trees|Tree trench/tree box]]
 
*[[Trees|Tree trench/tree box]]
*[[Swales|Swales with a bioinfiltration base]]
+
*[[Dry swale (Grass swale)|Dry swales with check dams]]
  
 
Additional BMPs that result in infiltration include [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_and_rainwater_harvest_and_use/reuse stormwater and rainwater harvest with irrigation] and [https://stormwater.pca.state.mn.us/index.php?title=Turf#Recommended_credits_for_impervious_surface_disconnection impervious surface disconnection]. For these BMPs infiltration typically occurs into turf or other vegetated areas. Disconnection of impervious surface does not qualify for credits for meeting the [https://stormwater.pca.state.mn.us/index.php/Construction_stormwater_permit Construction Stormwater permit]. Harvest BMPs do qualify for credit because they capture an instantaneous volume of water.
 
Additional BMPs that result in infiltration include [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_and_rainwater_harvest_and_use/reuse stormwater and rainwater harvest with irrigation] and [https://stormwater.pca.state.mn.us/index.php?title=Turf#Recommended_credits_for_impervious_surface_disconnection impervious surface disconnection]. For these BMPs infiltration typically occurs into turf or other vegetated areas. Disconnection of impervious surface does not qualify for credits for meeting the [https://stormwater.pca.state.mn.us/index.php/Construction_stormwater_permit Construction Stormwater permit]. Harvest BMPs do qualify for credit because they capture an instantaneous volume of water.
  
The links above take you to the main page for each BMP. Each BMP section has a page on pollutant credits. These [https://stormwater.pca.state.mn.us/index.php?title=Category:Calculating_credits credit pages] provide information on runoff volume and pollutant removal for the BMP, including credits that can be applied to meet a performance goal such as a Total Maximum Daily Load (TMDL).
+
The links above take you to the main page for each BMP. Each BMP section has a page on pollutant credits. These [https://stormwater.pca.state.mn.us/index.php?title=Category:Calculating_credits credit pages] provide information on runoff volume and pollutant removal for the BMP, including credits that can be applied to meet a performance goal such as a <span title="the amount of a pollutant from both point and nonpoint sources that a waterbody can receive and still meet water quality standards"> [https://stormwater.pca.state.mn.us/index.php?title=Total_Maximum_Daily_Loads_(TMDLs) '''total maximum daily load''']</span> (TMDL).
  
In soils where there are constraints on infiltration, BMPs may be designed with underdrains. Unless the BMP is lined, some water will infiltrate through the bottom and sides of the BMP. TP removal for the portion of captured runoff that infiltrates is 100 percent. Water draining to the underdrain undergoes some treatment. These BMPs are discussed in more detail in the filtration section below.
+
In soils where there are constraints on infiltration, BMPs may be designed with <span title="An underground drain or trench with openings through which the water may percolate from the soil or ground above"> '''underdrains'''</span>. Unless the BMP is [https://stormwater.pca.state.mn.us/index.php?title=Liners_for_stormwater_management lined], some water will infiltrate through the bottom and sides of the BMP. TP removal for the portion of captured runoff that infiltrates is 100 percent. Water draining to the underdrain undergoes some treatment. These BMPs are discussed in more detail in the filtration section below.
 +
 
 +
{{alert|Infiltration practices are among the most effective treatment practices for removing dissolved phosphorus. Although infiltrating water may transport dissolved phosphorus to shallow groundwater, this is only a concern when infiltration practices are located adjacent to sensitive receiving waters that have a significant baseflow component|alert-info}}
  
 
===Settling practices===
 
===Settling practices===
Line 139: Line 171:
  
 
Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for [[Stormwater ponds|constructed stormwater ponds]] and [[stormwater wetlands|constructed stormwater wetlands]].
 
Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for [[Stormwater ponds|constructed stormwater ponds]] and [[stormwater wetlands|constructed stormwater wetlands]].
 +
 +
{{alert|Constructed ponds and wetlands are generally not effective at removing dissolved phosphorus. Some uptake by plants may occur. Amendments such as aluminum can be added to retain phosphorus|alert-info}}
  
 
===Filtration practices===
 
===Filtration practices===
Filtration practices are typically used when infiltration practices are not feasible, such as areas with low infiltration soils or shallow bedrock (see section on [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_infiltration infiltration constraints]. Filtration practices include [[Bioretention|bioretention with underdrains]], [[Filtration|media filters]], and [[Filtration|swales]].  [[Vegetated filter strips]] are often used as a [[Pretreatment|pretreatment]] practice.
+
Filtration practices are typically used when infiltration practices are not feasible, such as areas with low infiltration soils or shallow bedrock (see section on [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_infiltration infiltration constraints]). Filtration practices include [[Bioretention|bioretention with underdrains]], [[Filtration|media filters]], and [[Filtration|swales]].  [[Vegetated filter strips]] are often used as a [[Pretreatment|pretreatment]] practice.
  
 
[[Filtration|Sand filters]] have removal rates of about 50 percent for TP. This is all considered to be particulate phosphorus. [https://stormwater.pca.state.mn.us/index.php?title=Iron_enhanced_sand_filter_%28Minnesota_Filter%29 Amendments] can be added to sand filters to remove dissolved phosphorus. This manual provides a credit of 60 percent removal of dissolved phosphorus, thus giving a TP removal of 77 percent for amended sand filters.
 
[[Filtration|Sand filters]] have removal rates of about 50 percent for TP. This is all considered to be particulate phosphorus. [https://stormwater.pca.state.mn.us/index.php?title=Iron_enhanced_sand_filter_%28Minnesota_Filter%29 Amendments] can be added to sand filters to remove dissolved phosphorus. This manual provides a credit of 60 percent removal of dissolved phosphorus, thus giving a TP removal of 77 percent for amended sand filters.
  
Filtration practices that utilize engineered media (bioretention, swales) have different removal efficiencies depending on the media and whether the media has been amended to remove dissolved phosphorus. Media that have high organic matter content will not effectively retain phosphorus and can leach phosphorus. These include Mixes A, B, E, and F. Mixes C and D have low organic matter contents and will attenuate phosphorus. The following sections in this manual are useful for determining the effectiveness of filtration practices with engineered media.
+
Filtration practices that utilize <span title="Engineered media is a mixture of sand, fines (silt, clay), and organic matter utilized in stormwater practices, most frequently in bioretention practices. The media is typically designed to have a rapid infiltration rate, attenuate pollutants, and allow for plant growth."> [https://stormwater.pca.state.mn.us/index.php?title=Design_criteria_for_bioretention#Materials_specifications_-_filter_media '''engineered media''']</span> (bioretention, swales) have different removal efficiencies depending on the media and whether the media has been amended to remove dissolved phosphorus. Media that have high organic matter content will not effectively retain phosphorus and can leach phosphorus. These include Mixes A, B, E, and F. Mixes C and D have low organic matter contents and will attenuate phosphorus. The following sections in this manual are useful for determining the effectiveness of filtration practices with engineered media.
 
*[https://stormwater.pca.state.mn.us/index.php?title=Design_criteria_for_bioretention#Materials_specifications_-_filter_media Materials specifications - filter media]
 
*[https://stormwater.pca.state.mn.us/index.php?title=Design_criteria_for_bioretention#Materials_specifications_-_filter_media Materials specifications - filter media]
 
*[[Soil amendments to enhance phosphorus sorption]]
 
*[[Soil amendments to enhance phosphorus sorption]]
Line 154: Line 188:
  
 
Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for [[Filtration|media filters and swales]], [[Green roofs|green roofs]], and [[Bioretention|bioretention]].
 
Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for [[Filtration|media filters and swales]], [[Green roofs|green roofs]], and [[Bioretention|bioretention]].
 +
 +
{{alert|Filtration practices that utilize engineered media leach phosphorus unless the organic matter content of the media is relatively low (30 mg-P/kg-media or lower). Both sand filters and biofiltration practices can be amended (e.g. iron) to retain dissolved phosphorus|alert-info}}
 +
 +
==Meeting TP water quality targets==
 +
{{alert|Many phosphorus goals are expressed as goals for total phosphorus (TP). Many stormwater practitioners focus on achieving TP targets by utilizing practices that are effective for removing particulate phosphorus but ineffective for removing dissolved phosphorus. Studies show that dissolved phosphorus is highly bioavailable while particulate phosphorus is much less bioavailable. Consequently, achieving TP targets may have limited impacts on receiving waters. Practitioners should attempt to characterize runoff before selecting treatment practices.|alert-warning}}
 +
 +
Information on this page can be used to help meet water quality targets. Water quality targets are established for various purposes including meeting Clean Water Act (CWA) requirements, meeting local water quality goals or requirements, and meeting non-regulatory targets. CWA requirements include antidegradation, TMDL limits, and NPDES permit requirements. Each of these are described below.
 +
 +
{{alert|Note that information presented in the Stormwater Manual can be used to meet NPDES permit requirements. This includes information on all BMPs discussed in the Manual unless otherwise noted. Check with MPCA's Stormwater Program for applicability of information not contained in the Manual, including BMPs and BMP credits.|alert-info}}
 +
 +
===Antidegradation===
 +
Water quality standards include an <span title="antidegradation means that no pollutant discharges or activities will be permitted if these may cause surface waters already meeting water quality standards to drop below those standards."> '''antidegradation'''</span> policy and implementation method. The <span title="Water quality standards (WQS) are provisions of state, territorial, authorized tribal or federal law approved by EPA that describe the desired condition of a water body and the means by which that condition will be protected or achieved."> '''water quality standards'''</span> regulation requires States and Tribes to establish a three-tiered antidegradation program to protect existing water quality and water uses in receiving waters (see [http://water.epa.gov/scitech/swguidance/standards/adeg.cfm]).
 +
 +
Compliance with Minimum Control Measure (MCM) 5 of the MS4 permit constitutes compliance with antidegradation requirements. The permit requires no net increase in discharges of volume, total phosphorus (TP) and total suspended solids (TSS) for new development, while a reduction in these are required for redevelopment projects covered under the permit.  Practices that [https://stormwater.pca.state.mn.us/index.php?title=BMPs_for_stormwater_infiltration infiltrate] or [https://stormwater.pca.state.mn.us/index.php?title=Stormwater_and_rainwater_harvest_and_use/reuse capture and reuse stormwater runoff] are typically used to meet these permit requirements because they help meet the volume requirements.
 +
 +
===Total Maximum Daily Loads (TMDLs)===
 +
The 2016 impaired water list includes 358 lakes or reservoirs and 44 river or stream stretches impaired for nutrrient/eutrophication biological indicators. Phosphorus is likely to be the surrogate pollutant for most of these impairments. Other impairments, such as those for dissolved oxygen, may also be associated with excessive TP loads. Click [https://www.pca.state.mn.us/water/minnesotas-impaired-waters-list here] to link to MPCA's impaired waters website.
 +
 +
The MS4 permit requires permittees to demonstrate progress toward meeting applicable Wasteload Allocations in U.S. EPA-approved TMDLs. General information on meeting TMDL requirements in NPDES permits is found [http://stormwater.pca.state.mn.us/index.php/MS4_PART_III.STORMWATER_POLLUTION_PREVENTION_PROGRAM_%28SWPPP%29#E._Discharges_to_Impaired_Waters_with_a_USEPA-Approved_TMDL_that_Includes_an_Applicable_WLA here], while reporting requirements are found [http://stormwater.pca.state.mn.us/index.php/Guidance_for_completing_the_TMDL_reporting_form#TMDL_requirements_in_stormwater_permits here]. Below is additional information that may be useful.
 +
*[http://stormwater.pca.state.mn.us/index.php/Forms_and_guidance_for_TMDLs Forms and guidance for TMDLs]: includes information on completing the TMDL Annual Report form and other guidance documents.
 +
*Information on modeling, including [[Available stormwater models and selecting a model]] and [[Detailed information on specific models]].
 +
*[[Information on pollutant removal by BMPs]]. Pollutant removal information is limited to structural BMPs. Each BMP included in the manual also has a [https://stormwater.pca.state.mn.us/index.php?title=Category:Calculating_credits section on credits], which provides useful information for determining pollutant removal for TP for that BMP.
 +
 +
Permittees with required reductions in TP loading should consider implementing a [[Using the treatment train approach to BMP selection|treatment train approach]].
  
 
==Stormwater design recommendations to enhance phosphorus removal==
 
==Stormwater design recommendations to enhance phosphorus removal==
Line 159: Line 217:
  
 
==References==
 
==References==
 +
*Abell, J.M., and D.P. Hamilton. 2012. [https://www.tandfonline.com/doi/full/10.1080/00288330.2013.792851 Bioavailability of phosphorus transported during storm flow to a eutrophic, polymictic lake]. New Zealand Journal of Marine and Freshwater Research. 47:4:481-489.
 +
*Ellison, M.E,, and M.T. Brett. 2006. [https://www.sciencedirect.com/science/article/pii/S0043135406000352 Particulate phosphorus bioavailability as a function of stream flow and land cover]. Water Research. 40:1258 – 1268
 
*Hopke P.K., Lamb R.E., and F.S. Natusch. (1980) ''Multielemental characterization of urban roadway dust''. Environ Sci Technol 14:164–172.
 
*Hopke P.K., Lamb R.E., and F.S. Natusch. (1980) ''Multielemental characterization of urban roadway dust''. Environ Sci Technol 14:164–172.
 
*Jeje, Yetunde. 2006. [https://ia600200.us.archive.org/5/items/exportcoefficien00jeje_0/exportcoefficien00jeje_0.pdf Export Coefficients for Total Phosphorus, Total Nitrogen and Total Suspended Solids in the Southern Alberta Region - A Review of Literature]. Alberta Environment.
 
*Jeje, Yetunde. 2006. [https://ia600200.us.archive.org/5/items/exportcoefficien00jeje_0/exportcoefficien00jeje_0.pdf Export Coefficients for Total Phosphorus, Total Nitrogen and Total Suspended Solids in the Southern Alberta Region - A Review of Literature]. Alberta Environment.
 
*Law, N.L., DiBlasi, K., and U. Ghosh  2008.  [https://www.worldsweeper.com/Street/Studies/CWPStudy/CBStreetSweeping.pdf Deriving Reliable Pollutant Removal Rates for Municipal Street Sweeping and Storm Drain Cleanout Programs in the Chesapeake Bay Basin]. Center for Watershed Protection.
 
*Law, N.L., DiBlasi, K., and U. Ghosh  2008.  [https://www.worldsweeper.com/Street/Studies/CWPStudy/CBStreetSweeping.pdf Deriving Reliable Pollutant Removal Rates for Municipal Street Sweeping and Storm Drain Cleanout Programs in the Chesapeake Bay Basin]. Center for Watershed Protection.
*Lin, J.P. 2004. [https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=1&ved=0ahUKEwjvjuyZ943SAhXF5oMKHX4eAAEQFggaMAA&url=http%3A%2F%2Fwww.dtic.mil%2Fcgi-bin%2FGetTRDoc%3FAD%3DADA430436&usg=AFQjCNFTeVQbSqCLn6Pjtyy4B4cLt5uidQ&bvm=bv.146786187,d.amc&cad=rja Review of Published Export Coefficient and Event Mean Concentration (EMC) Data]. WRAP Technical Notes Collection (ERDC TN-WRAP-04-3), U.S. Army Engineer Research and Development Center, Vicksburg, MS.  
+
*Lin, J.P. 2004. [https://apps.dtic.mil/sti/pdfs/ADA430436.pdf Review of Published Export Coefficient and Event Mean Concentration (EMC) Data]. WRAP Technical Notes Collection (ERDC TN-WRAP-04-3), U.S. Army Engineer Research and Development Center, Vicksburg, MS.  
 
*Line, D.E., M. B. Shaffer, J. D. Blackwell. 2011. ''Sediment Export from a Highway Construction Site in Central North Carolina''. Transactions of the ASABE. 54(1): 105-111.
 
*Line, D.E., M. B. Shaffer, J. D. Blackwell. 2011. ''Sediment Export from a Highway Construction Site in Central North Carolina''. Transactions of the ASABE. 54(1): 105-111.
 
*Line, D.E., J. Blackwell, M. Shaffer, and J. Spooner. 2009. ''Demonstrating and Evaluating Low Impact Development Techniques''. North Carolina State University Biological and Agricultural Engineering Dept. 15 pp.
 
*Line, D.E., J. Blackwell, M. Shaffer, and J. Spooner. 2009. ''Demonstrating and Evaluating Low Impact Development Techniques''. North Carolina State University Biological and Agricultural Engineering Dept. 15 pp.
 
*Lubliner, Brandi. 2007. [https://fortress.wa.gov/ecy/publications/documents/0703027.pdf Phosphorus Concentrations in Construction Stormwater Runoff: A Literature Review]. Washington State Department of Ecology. Publication No. 07-03-027.
 
*Lubliner, Brandi. 2007. [https://fortress.wa.gov/ecy/publications/documents/0703027.pdf Phosphorus Concentrations in Construction Stormwater Runoff: A Literature Review]. Washington State Department of Ecology. Publication No. 07-03-027.
 +
*Prestigiacomo, A.R., S.W. Effler, D. A. Matthews, M. T. Auer, B. E. Downer, A. Kuczynski and M. T. Walter. 2016. [https://onlinelibrary.wiley.com/doi/full/10.1111/1752-1688.12366 Apportionment of Bioavailable Phosphorus Loads Entering Cayuga Lake, New York]. Journal of American Water Works Technical Paper 14-0155-P. 50p.
 
*Selbig, W.R. and R. T. Bannerman. 2007. [http://pubs.usgs.gov/sir/2007/5156/#a Evaluation of Street Sweeping as a Stormwater-Quality-Management Tool in Three Residential Basins in Madison, Wisconsin]. USGS Scientific Investigations Report 2007–5156.
 
*Selbig, W.R. and R. T. Bannerman. 2007. [http://pubs.usgs.gov/sir/2007/5156/#a Evaluation of Street Sweeping as a Stormwater-Quality-Management Tool in Three Residential Basins in Madison, Wisconsin]. USGS Scientific Investigations Report 2007–5156.
*Sutherland, R. 2011. [https://foresternetwork.com/daily/water/stormwater-management/street-sweeping-101/ Street Sweeping 101]. Stormwater. January-February 2011.
+
*Sutherland, R. 2011. [https://www.stormh2o.com/bmps/article/13026099/street-sweeping-101 Street Sweeping 101]. Stormwater. January-February 2011.
 
*Tipping, Benham S., Boyle J.F., Crow P., Davies J., Fischer U., Guyatt H., Helliwell R., Jackson-Blake L., Lawlor A.J., Monteith D.T., Rowe E.C., Toberman H. 2014. ''Atmospheric deposition of phosphorus to land and freshwater''. Environ Sci Process Impacts. 2014 Jul;16(7):1608-17.
 
*Tipping, Benham S., Boyle J.F., Crow P., Davies J., Fischer U., Guyatt H., Helliwell R., Jackson-Blake L., Lawlor A.J., Monteith D.T., Rowe E.C., Toberman H. 2014. ''Atmospheric deposition of phosphorus to land and freshwater''. Environ Sci Process Impacts. 2014 Jul;16(7):1608-17.
 
*United States Environmental Protection Agency. 1999. [http://water.epa.gov/scitech/wastetech/guide/stormwater/#report Preliminary Data Summary of Urban Storm Water Best Management Practices]. EPA-821-R-99-012.
 
*United States Environmental Protection Agency. 1999. [http://water.epa.gov/scitech/wastetech/guide/stormwater/#report Preliminary Data Summary of Urban Storm Water Best Management Practices]. EPA-821-R-99-012.
 +
*Uusitalo, R., E. Turtola, M. Puustinen, M. Paasonen-Kiveka¨s, and J. Uusi-Ka¨mppa. 2003.  [https://www.semanticscholar.org/paper/Contribution-of-particulate-phosphorus-to-runoff-Uusitalo-Turtola/54189c9219e05e1b9c66b35a5af7799dc4d4e9a8 Contribution of Particulate Phosphorus to Runoff Phosphorus Bioavailability. Journal of Environmental Quality].
 
*Waschbusch, R.J., W.R. Selbig, and R.T. Bannerman. 1999. [https://stormwater.pca.state.mn.us/index.php?title=File:USGS_paper_sources_of_phosphorus.pdf Sources of Phosphorus in Stormwater and Street Dirt from Two Urban Residential Basins In Madison, Wisconsin, 1994–95]. U.S. Geological Survey Water-Resources Investigations Report 99–4021.
 
*Waschbusch, R.J., W.R. Selbig, and R.T. Bannerman. 1999. [https://stormwater.pca.state.mn.us/index.php?title=File:USGS_paper_sources_of_phosphorus.pdf Sources of Phosphorus in Stormwater and Street Dirt from Two Urban Residential Basins In Madison, Wisconsin, 1994–95]. U.S. Geological Survey Water-Resources Investigations Report 99–4021.
 
*Wolman, M. G. and Schick, A. P.. 1967. ''Effects of construction on fluvial sediment; urban and suburban areas of Maryland''. Water Resources Res., v. 3, No. 2.
 
*Wolman, M. G. and Schick, A. P.. 1967. ''Effects of construction on fluvial sediment; urban and suburban areas of Maryland''. Water Resources Res., v. 3, No. 2.
 +
<noinclude>
 +
 +
[[Category:Level 2 - Pollutants/Phosphorus]]
 +
</noinclude>

Latest revision as of 13:56, 11 February 2023

PAGE SUMMARY
The following list summarizes the important points on this page
  • Phosphorus in stormwater occurs in dissolved and particulate forms. Dissolved forms typically are more than 90% bioavailable, while paarticulate forms are typically less than 25% bioavailable. For a discussion of dissolved and particulate fractions in stormwate rrunoff, see Ratios of particulate to dissolved phosphorus
  • Typical concentrations of total phosphorus (TP) in stormwater vary with land use, ranging from about 0.19 mg/L from open space areas to about 0.32 mg/L for residential areas. TP export from urban land uses are typically 1-3 lb/ac/yr.
  • Stormwater management should utilize a treatment train approach and focus on dissolved phosphorus in areas where contributions of dissolved phosphorus are significant.
  • Infiltration, pollution prevention, and use of amendments are effective for dissolved phosphorus
  • Erosion control, filtration, and sedimentation practices are effective for particulate phosphorus but less effective for dissolved phosphorus
image
image of eutrophication
Photo of a eutrophic lake, a result of excessive phosphorus loading.

The United States Geological Survey states: "Phosphorus is a common constituent of agricultural fertilizers, manure, [urban runoff], and organic wastes in sewage and industrial effluent. It is an essential element for plant life, but when there is too much of it in water, it can speed up eutrophication (a reduction in dissolved oxygen in water bodies caused by an increase of mineral and organic nutrients) of rivers and lakes." Phosphorus in stormwater runoff can generally be divided into the fraction associated with sediment, called particulate phosphorus, and the fraction dissolved in water, called dissolved or soluble phosphorus. Total phosphorus is the sum of particulate and dissolved phosphorus and includes the total amount of phosphorus in both organic and inorganic forms. Orthophosphate measures phosphorus that is most immediately biologically available. Most of the soluble phosphorus in stormwater is usually present in the orthophosphate form.

This article provides information on phosphorus in urban stormwater, including a discussion of sources of phosphorus and management strategies for minimizing phosphorus loading from urban stormwater runoff to surface water. For more information on phosphorus in water, click on these links: [1], [2], [3], [4], [5].

Information: Blue alert boxes are used throughout this page to identify best practices for minimizing dissolved phosphorus. Dissolved phosphorus has the greatest impact on receiving waters and minimizing or treating for dissolved phosphorus in runoff should be a priority for protecting receiving waters.

Forms of phosphorus found in stormwater and natural waters

image of phosphorus speciation
Schematic showing analysis for different forms of phosphorus in water. Filtered phosphorus is considered to represent dissolved phosphorus, while unfiltered phosphorus represents all phosphorus. Particulate phosphorus is the difference between filtered and unfiltered.

Phosphorus in water is often classified as dissolved (soluble) or particulate (attached to or a component of particulate matter) phosphorus. This nomenclature is somewhat ambiguous, however, as dissolved phosphorus consists of multiple forms of phosphorus, including phosphorus attached to other materials. Dissolved phosphorus is typically identified as phosphorus passing through a 0.45 micron filter. It is this dissolved fraction that is considered to be most bioavailable and most difficult to treat. Understanding phosphorus behavior is further complicated by environmental conditions, particularly oxidation-reduction (redox) conditions, since a portion of particulate phosphorus will release phosphorus under anoxic (reducing) conditions.

Other terms encountered or forms of phosphorus discussed in the literature include the following.

  • Total phosphorus (TP) is a measure of all the forms of phosphorus, dissolved or particulate, that are found in a sample.
  • Inorganic phosphate is phosphate not associated with organic material. Types of inorganic phosphate include orthophosphate (PO4-2) and polyphosphates.
  • Organic phosphate is phosphate that is bound to plant or animal tissue.
  • Phosphate or orthophosphate refers to the phosphate molecule by itself.
  • Reactive phosphorus is the phosphorus associated with the test for orthophosphate. It consists mostly of orthophosphate but includes a small fraction of other forms.
  • Soluble reactive phosphorus is a measure of orthophosphate, the filterable (soluble, inorganic) fraction of phosphorus, the form directly taken up by plant cells.
  • Bioavailable phosphorus is the sum of immediately available phosphorus, which can be transformed into an available form by naturally occurring processes.

The following links provide discussion of phosphorus in stormwater.

References for phosphorus forms and testing includes the following.

Bioavailability of different forms of phosphorus

An important consideration in treating stormwater runoff is the form of the phosphorus. As stated above, dissolved phosphorus is considered to be more bioavailable than particulate forms of phosphorus. Below is a summary of some studies on bioavailability of phosphorus.

  • About 95% of dissolved phosphorus transported to Lake Erie is bioavailable to algae, while only about 30% of the particulate phosphorus attached to eroded sediment is bioavailable (Lake Erie Algae).
  • Ellison and Brett (2006) found on average only 20% of the particulate phosphorus transported in runoff from urban settings was biologically available.
  • Abell and Hamilton (2012) found that about 25% of particulate phosphorus in a stream dominated by stormwater runoff was bioavailable.
  • Prestigiacomo et al. found 10-20% of particulate phosphorus was bioavailable, compared to more than 90% of dissolved phosphorus being bioavailable. Bioavailable phosphorus in the particulate fraction increased somewhat with time after sampling, but never exceeded 30%.
  • Uusitalo et al. (2003) found 6-10% of particulate phosphorus was bioavailable, but that 34-56% was redox-sensitive, meaning it could become bioavailable under anoxic (reducing) conditions. Other papers corroborate these findings, indicating that a significant portion of particulate phosphorus can become bioavailable under anoxic conditions ([6], [7], [8], [9])

Source and concentrations of phosphorus in urban stormwater

Sources of phosphorus in urban runoff include plant and leaf litter, soil particles, pet waste, road salt, fertilizer, and atmospheric deposition of particles. Lawns and roads account for the greatest loading. For example, Waschbusch et. al (1999) found that lawns and roads contributed about 80 percent of total and dissolved phosphorus loading. Land use affects the contribution from different sources, with lawns and leaf litter being more important in residential areas and roads being more important in commercial and industrial areas. Atmospheric sources of particles may derive from outside of the river basin (Hopke et al. 1980; Tipping et al., 2014).

The fraction of total phosphorus in dissolved form varies with the source of phosphorus, which in turn varies with season and land use. The dissolved fraction may exceed 50 percent when the source is plant litter, fertilizer, and animal waste, while the dissolved fraction may be as low as 25 percent when the source is predominantly sediment (Waschbusch et. al, 1999). For more information on phosphorus in urban stormwater, see the section on contribution of tree leaves, seeds, and flowers to phosphorus in urban runoff. For a detailed discussion of dissolved and particulate fractions in runoff, link here.

Concentrations of phosphorus in urban stormwater runoff are highly variable. The following table provides data on event mean concentrations of total phosphorus in stormwater, by land use. For more information on phosphorus concentrations in stormwater runoff, see Event mean concentrations of total and dissolved phosphorus in stormwater runoff.

Event mean concentrations for total phosphorus.
Link to this table

Land cover/land use Range (mg/L) Recommended value (mg/L) Notes
Commercial 0.20 - 0.34 0.200 If applicable to models being used, adjust curve numbers/runoff coefficients when calculating loads
Industrial 0.23 - 0.55 0.235
  • If applicable to models being used, adjust curve numbers/runoff coefficients when calculating loads
  • Adjust upward if specific phosphorus sources exist
Residential 0.26 - 0.38 0.325 Concentrations vary widely depending on local conditions
High-density/Multi-family residential 0.28 - 0.40 Calculate1
  • Insufficient information to recommend a specific emc
  • Concentrations vary widely depending on local conditions
Medium density residential 0.18 - 0.40 Calculate1
  • Insufficient information to recommend a specific emc
  • Concentrations vary widely depending on local conditions
Low density residential 0.24 - 0.40 Calculate1
  • Insufficient information to recommend a specific emc
  • Concentrations vary widely depending on local conditions
Freeways/transportation 0.25 - 0.45 0.280
  • Concentrations vary widely depending on inputs
  • Adjust upward for areas receiving large inputs of road salt or sediment or having very heavy traffic loads
  • Adjust downward for low traffic areas or areas with reduced inputs (e.g. little road salt application, limited truck traffic)
Mixed 0.16 - 0.84 0.290
  • Residential land use was the primary land use in most studies that cited values for mixed land use
  • If the study area can be delineated into specific land uses and impervious area for each land use is know, we recommend calculating the emc
Parks and recreation Use value for open space or calculate
  • emc will be a function of vegetative cover
  • Adjust upward if street tree canopy cover is high or pervious areas are primarily grass on compacted soils
Open space 0.12 - 0.31 0.190
Conventional roof 0.01 - 0.20 0.030
Institutional 0.14 - 0.422 See note
  • Use low values in range (0.200 mg/L or less) for facilities such as campuses, where there is considerable pervious area
  • Use high values in range (0.30 mg/L or greater) for areas with considerable impervious surface, such as sports facilities or facilities with large parking areas
Forest/shrub/grassland 0.03 - 0.45 0.090 Concentrations are likely to vary with season in areas with fall leaf drop
Open water and wetlands see Notes (next column)
  • If data exist, use the phosphorus concentration for the water body of interest
  • If data for a specific lake do not exist, use data from similar lakes in the area
  • emcs for wetlands will typically be higher than for lakes in an area. Consider using a value equal to 2 times the value for lakes in an area.
Cropland (row crops) 0.126-1.348 2 Median from our review = 0.533
Pasture 0.35-0.45 2

1The link takes you to information on calculating event mean concentrations for areas with multiple land uses.
2Our literature review was not extensive enough to warrant a specific recommend emc for this land use


Total phosphorus (TP) export varies with the amount of runoff and is calculated by multiplying the TP concentration by the volume of runoff. The Simple Method can be used to estimate TP loading as a function of different land uses. Export coefficients are presented in the literature for different land uses. The data are highly variable as a result of the differences in impervious surface, even within specific land uses. Typical annual TP export coefficients are shown below (data adapted from studies cited in Lin (2004) and Jeje (2006)).

Land use Range (lb/ac/yr) Recommended (lb/ac/yr)
Native grass 0.04-0.32 0.10
Forest 0.04-0.27 0.13
Pasture 0.27-0.89 0.70
Corn/soybean 1.8-3.4 2.2
Mixed agriculture 0.44-0.98 0.70
Low density residential 1.1
High density residential 1.3
Commercial 2.0
Highways 3.1

Stormwater management for phosphorus

photo illustrating a watershed scale treatment train approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff.
Watershed scale stormwater management approach using a multi-BMP approach to managing the quantity and quality of stormwater runoff. The BMP sequence starts with pollution prevention and progresses through source control, on-site treatment, and regional treatment before the runoff water is discharged to a receiving water. On-site and regional practices treat stormwater runoff and can be incorporated into a stormwater treatment train.

Management of urban stormwater to control or reduce TP concentrations and loading should focus on identifying the most important sources and employing specific practices to address those sources. If significant reductions in TP loading are required or desired, a treatment train approach should be utilized. The treatment train approach for TP focuses on implementing the following hierarchy of practices:

Construction stormwater

Data on TP loading from construction stormwater sites is limited. TSS concentrations in runoff from construction sites typically greatly exceed concentrations from other urban land uses and generally exceed 1000 milligrams per liter. Sediment export from construction sites typically ranges from 2000 to 16000 pounds per acre per year (Line et al., 2009; Line et al., 2011; Wolman and Schick, 1967). However, one study in Washington state showed TP concentrations ranged from 0.01 to 0.16 milligrams per liter in runoff from construction sites, with a median of 0.095 milligrams per liter. These are relatively low concentrations considering the amount of sediment leaving construction sites. Other potential sources of phosphorus on a construction site result from land treatment practices employed by the construction site personnel, such as fertilizers, tackifier, hydroseed, wood mulch, or other types of applications. These products could be evaluated for their phosphorus content. Erosion protection and sediment control practices described in this manual should be employed at construction sites.

Information: At most construction sites, most phosphorus will be in particulate form, which is typically easier to treat and less bioavailable than dissolved forms. To minimize dissolved phosphorus export, minimze the use of fertilizers, use slow release fertilizers, and avoid organic materials, such as compost, than can release soluble phosphorus.

Pollution prevention and source control

These practices reduce the amount of TP generated or remove TP prior to it being entrained in runoff. These are summarized below for residential, municipal, and industrial sources.

Information: Pollution prevention practices are among the most effective methods for minimizing dissolved phosphorus loads since these practices typically address important sources of dissolved phosphorus.

Prevention practices for residential areas

The following table summarizes residential prevention practices that are effective at reducing TP concentrations. The table indicates the relative effectiveness of each practice and provides a short description of the practice. TP removal efficiencies are not established for these BMPs.

Residential pollution prevention methods effective for controlling or reducing phosphorus.
Link to this table

Practice Relative effectiveness Method Image1
Fertilizer and pesticide management High Reduce or eliminate the need for fertilizer and pesticides by practicing natural lawn care, planting native vegetation, and limiting chemical use; follow Minnesota Statutes Chapter 18C and federal regulatory requirements on fertilizer and pesticide storage and application if used.
Fertilizer pesticide management.jpg
Litter and animal waste control High Properly dispose of pet waste and litter in a timely manner and according to local ordinance requirements.
Litter animal waste control.jpg
Yard Waste Management High Prevent yard waste from entering storm sewer systems and water bodies by either composting or using curbside pickup services and avoiding accumulation of yard waste on impervious surfaces; keep grass clippings and leaves out of the street.
Yard waste management.jpg
Better Car and Equipment Washing Moderate Wash cars less often and on grassy areas using phosphorus free detergents and non-toxic cleaning products or use commercial car washes to prevent dirty wash water from flowing to storm sewer systems and water bodies.
Better car washing.jpg
Septic tank maintenance High
Native Landscaping High Reduce turf areas by planting native species to reduce and filter pollutant-laden runoff and prevent the spread of invasive, non-native plant species into the storm sewer system.
Native landscaping.jpg
Better Sidewalk and Driveway Deicing Moderate Reduce or eliminate the need for deicing products by manually clearing sidewalks and driveways prior to deicer use; use environmentally-friendly deicing products when possible, apply sparingly and store properly if used.
Better sidewalk driveway deicing.jpg
Exposed Soil Repair High Use native vegetation or grass to cover and stabilize exposed soil on lawns to prevent sediment wash off.
Exposed soil repair.jpg
Healthy Lawns Moderate Maintain thick grass planted in organic-rich soil to a height of at least 3 inches to prevent soil erosion, filter stormwater contaminants, and absorb airborne pollutants; limit or eliminate chemical use and water and repair lawn as needed
Healthy lawns.JPG

1 Photo credits


Prevention practices for municipalities

The following table summarizes municipal prevention practices that are effective at reducing TP concentrations. The table indicates the relative effectiveness of each practice and provides a short description of the practice. TP removal efficiencies are not established for these BMPs.

Municipal prevention practices for TP.
Link to this table

Practice Relative effectiveness Method Image1
Proper Vehicle Management High Ensure that vehicles are fueled, maintained, washed and stored in a manner that prevents the release of harmful fluids, including oil, antifreeze, gasoline, battery acid, hydraulic and transmission fluids, and cleaning solutions.
Proper vehicle management.jpg
Better Turf Management High Ensure that mowing, fertilization, pesticide application, and irrigation are completed in ways that will prevent or reduce grass clippings, sediment, and chemicals from entering storm sewer systems; use native vegetation where possible.
Better turf management.jpg
Sanitary Sewer Maintenance High Regularly inspect and flush sanitary pipes to ensure that there are no leaks in the system and that the system is properly functioning.
Sanitary storm sewer maintenance.jpg
Litter and Animal Waste Control High Mandate litter and pet waste cleanup within the community and control waste-generating wildlife, such as geese; provide waste containers for litter and pet waste in public areas.
Litter animal waste control.jpg
Temporary Construction Sediment Control Moderate Implement and encourage practices to retain sediment within construction project area; see Temporary Construction Erosion and Sediment Control Factsheets for additional information
Temporary construction sediment control.jpg
Wind Erosion Control Moderate Institute a local program for wetting of open construction surfaces and other sources for windblown pollutants.
Wind erosion control.jpg
Streambank Stabilization2 Moderate Repair erosion occurring on a streambank of lakeshore in a timely manner; inspect bank areas for ice damage in the spring.
Streambank stabilization.jpg
Material Storage Control Moderate Reduce or eliminate spill and leakage loss by properly inspecting, containing, and storing hazardous materials and having a cleanup plan that can be quickly and efficiently implemented.
Material storage control.jpg
Dumpster and landfill management Moderate Ensure that contaminated material is contained to prevent solid and/or liquid waste from being washed into storm sewer systems or water bodies.
Dumpster and landfill management.JPG
Better Street and Parking Lot Cleaning Moderate Maintain streets and parking lots frequently and especially in the spring by sweeping, picking up litter, and repairing deterioration; pressure wash pavement only as needed and avoid using cleaning agents.
Better street parking lot cleaning.jpg
Storm Sewer System Maintenance Moderate Regularly clean debris from storm sewer inlets, remove sediment from catch basin sumps, and remove any illicit connections to storm sewer systems.
Storm sewer system maintenance.jpg
Public Education Moderate Label storm drains to indicate that no dumping is allowed and institute pollution prevention programs to educate and implement needed community practices.
Public education.jpg
Staff, Employee, and Volunteer Education Moderate Provide internal training for staff and provide direction to hired employees or volunteers regarding pollution prevention techniques to be used during work activites.
Staff employee volunteer education.jpg

1 Photo credits
2Reductions in pollutant loading associated with this BMP are not eligible for credit toward NPDES permit requirements unless the stabilization is above the ordinary high water mark (i.e. the work is not completed within a Water of the State), prior to a permittee's discharge, and the load reduced from this action is included in a Wasteload Allocation in a U.S. EPA-approved TMDL.


Prevention practices for industrial sources

The following table summarizes industrial prevention practices that are effective at reducing TP concentrations. The table indicates the relative effectiveness of each practice and provides a short description of the practice. TP removal efficiencies are not established for these BMPs.

Industrial prevention practices for TP.
Link to this table

Practice Relative effectiveness Method Image1
Better Turf Management High Ensure that mowing, fertilization, pesticide application, and irrigation are completed in ways that will prevent or reduce grass clippings, sediment, and chemicals from entering storm sewer systems; use native vegetation where possible.
Better turf management.jpg
Proper Vehicle Management High Ensure that vehicles are fueled, maintained, washed and stored in a manner that prevents the release of harmful fluids, including oil, antifreeze, gasoline, battery acid, hydraulic and transmission fluids, and cleaning solutions.
Proper vehicle management.jpg
Sanitary Sewer Maintenance High Regularly inspect and flush sanitary pipes to ensure that there are no leaks in the system and that the system is properly functioning.
Sanitary storm sewer maintenance.jpg
Temporary Construction Sediment Control Moderate Implement and encourage practices to retain sediment within construction project area; see Temporary Construction Erosion and Sediment Control Factsheets for additional information
Temporary construction sediment control.jpg
Wind Erosion Control Moderate Institute a local program for wetting of open construction surfaces and other sources for windblown pollutants.
Wind erosion control.jpg
Material Storage Control Moderate Reduce or eliminate spill and leakage loss by properly inspecting, containing, and storing hazardous materials and having a cleanup plan that can be quickly and efficiently implemented.
Material storage control.jpg
Dumpster and landfill management Moderate Ensure that contaminated material is contained to prevent solid and/or liquid waste from being washed into storm sewer systems or water bodies.
Dumpster and landfill management.JPG
Better Street and Parking Lot Cleaning Moderate Maintain streets and parking lots frequently and especially in the spring by sweeping, picking up litter, and repairing deterioration; pressure wash pavement only as needed and avoid using cleaning agents.
Better street parking lot cleaning.jpg
Storm Sewer System Maintenance Moderate Regularly clean debris from storm sewer inlets, remove sediment from catch basin sumps, and remove any illicit connections to storm sewer systems.
Storm sewer system maintenance.jpg

1 Photo credits


Street sweeping

Information: The MPCA is currently working with the University of Minnesota to develop a street sweeping credit. Link to our Future Updates page for more information.

Street sweeping can be an effective practice for reducing sediment loading to surface water, which in turn reduces loading of particulate phosphorus. This Manual currently has a short page describing street sweeping practices as they relate to phosphorus management. The page includes a link to a calculator developed at the University of Minnesota. The calculator estimates reductions in wet and dry solids as a function of different management practices.

Several articles in the literature present results from street sweeping studies. Examples include the following.

  • Selbig and Bannerman (2007) discuss changes in pollutant loading for regenerative-air, vacuum-assist, high-frequency broom, and low-frequency broom sweeping practices.
  • Law et al. (2008) found for a given set of assumptions and sweeping frequencies, it is expected that the range in pollutant removal rates from street sweeping for total solids was 3 to 8 percent, with the lower end representing monthly street sweeping by a mechanical street sweeper and the upper end the pollutant removal efficiencies using regenerative air/vacuum street sweeper at weekly frequencies.
  • Sutherland (2011) provides a comprehensive summary of street sweeping, including information on effectiveness of different sweepers and factors affecting the performance of street sweeping.
Information: Properly timed street sweeping (e.g. during fall leaf drop) can be a very effective method of reducing dissolved phosphorus loads since leaves are an important source of dissolved phosphorus

Pretreatment

Pretreatment is needed to protect infiltration and filtration BMPs from the build-up of trash, gross solids, and particulate matter. When the velocity of stormwater decreases, sediment and solids drop out. If pretreatment is not provided, this process will occur in the infiltration or filtration cell, resulting in long-term clogging and poor aesthetics. Therefore, pretreatment is a required part of the design for infiltration and filtration BMPs. There are three typical methods for pretreatment: Vegetated filter strips (VFS), forebays, and vegetated swales. These are discussed in the section on pretreatment.

Information: Pretreatment is generally ineffective for treating dissolved phosphorus, although devices that effectively screen coarse organic debris can be effective if cleaned during times when coarse organic loads are heavy (e.g. during leaf drop). Some pretreatment practices can be modified with an amendment to enhance removal of dissolved phosphorus.

Infiltration

Infiltration practices are structural Best Management Practices (BMPs) designed to capture stormwater runoff and allow the captured water to infiltrate into soils underlying the BMP. Infiltration BMPs are designed to capture a particular amount of runoff. For example, the construction stormwater permit requires that post-construction BMPs capture the first inch of runoff from new impervious surfaces, assuming there are no constraints to infiltration. BMPs designed to meet the construction stormwater permit are required to infiltrate captured water within 48 hours, with 24 hours recommended when discharges are to a trout stream.

TP removal is assumed to be 100 percent for all water that infiltrates. Any water bypassing the BMP does not receive treatment. Examples of infiltration BMPs, with links to appropriate sections in the Manual, include the following.

Additional BMPs that result in infiltration include stormwater and rainwater harvest with irrigation and impervious surface disconnection. For these BMPs infiltration typically occurs into turf or other vegetated areas. Disconnection of impervious surface does not qualify for credits for meeting the Construction Stormwater permit. Harvest BMPs do qualify for credit because they capture an instantaneous volume of water.

The links above take you to the main page for each BMP. Each BMP section has a page on pollutant credits. These credit pages provide information on runoff volume and pollutant removal for the BMP, including credits that can be applied to meet a performance goal such as a total maximum daily load (TMDL).

In soils where there are constraints on infiltration, BMPs may be designed with underdrains. Unless the BMP is lined, some water will infiltrate through the bottom and sides of the BMP. TP removal for the portion of captured runoff that infiltrates is 100 percent. Water draining to the underdrain undergoes some treatment. These BMPs are discussed in more detail in the filtration section below.

Information: Infiltration practices are among the most effective treatment practices for removing dissolved phosphorus. Although infiltrating water may transport dissolved phosphorus to shallow groundwater, this is only a concern when infiltration practices are located adjacent to sensitive receiving waters that have a significant baseflow component

Settling practices

Information: Note that we refer to constructed ponds and constructed wetlands in this section. Natural ponds and wetlands are not stormwater treatment practices and are therefore not included in this discussion.

If prevention, source control and infiltration practices cannot fully meet protection or restoration targets for stormwater, settling and filtration practices may be used. Settling practices include constructed stormwater ponds, including variants, and constructed stormwater wetlands, including variants. Manufactured devices and forebays are both settling practices but are primarily used for pretreatment.

Constructed ponds are effective at removing particulate material, with TSS removal rates ranging from 60 to 90 percent depending on the design. Constructed wetlands are also very effective at removing TSS, with removal rates ranging from 39 to 81 percent depending on the design. Assuming particulate phosphorus accounts for about 55 percent of total phosphorus (TP), and no dissolved phosphorus is removed by constructed ponds or constructed wetlands, TP removal is approximately 50 percent in ponds and 40 percent in wetlands. Poorly designed or poorly functioning ponds and wetlands can export dissolved phosphorus.

Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for constructed stormwater ponds and constructed stormwater wetlands.

Information: Constructed ponds and wetlands are generally not effective at removing dissolved phosphorus. Some uptake by plants may occur. Amendments such as aluminum can be added to retain phosphorus

Filtration practices

Filtration practices are typically used when infiltration practices are not feasible, such as areas with low infiltration soils or shallow bedrock (see section on infiltration constraints). Filtration practices include bioretention with underdrains, media filters, and swales. Vegetated filter strips are often used as a pretreatment practice.

Sand filters have removal rates of about 50 percent for TP. This is all considered to be particulate phosphorus. Amendments can be added to sand filters to remove dissolved phosphorus. This manual provides a credit of 60 percent removal of dissolved phosphorus, thus giving a TP removal of 77 percent for amended sand filters.

Filtration practices that utilize engineered media (bioretention, swales) have different removal efficiencies depending on the media and whether the media has been amended to remove dissolved phosphorus. Media that have high organic matter content will not effectively retain phosphorus and can leach phosphorus. These include Mixes A, B, E, and F. Mixes C and D have low organic matter contents and will attenuate phosphorus. The following sections in this manual are useful for determining the effectiveness of filtration practices with engineered media.

Caution: Green roofs do not receive a phosphorus credit because they typically leach phosphorus in the first years after construction. They may retain phosphorus as they age.

Information on design, construction, operation and maintenance, credits, and other characteristics of these BMPs can be found on the main pages for media filters and swales, green roofs, and bioretention.

Information: Filtration practices that utilize engineered media leach phosphorus unless the organic matter content of the media is relatively low (30 mg-P/kg-media or lower). Both sand filters and biofiltration practices can be amended (e.g. iron) to retain dissolved phosphorus

Meeting TP water quality targets

Caution: Many phosphorus goals are expressed as goals for total phosphorus (TP). Many stormwater practitioners focus on achieving TP targets by utilizing practices that are effective for removing particulate phosphorus but ineffective for removing dissolved phosphorus. Studies show that dissolved phosphorus is highly bioavailable while particulate phosphorus is much less bioavailable. Consequently, achieving TP targets may have limited impacts on receiving waters. Practitioners should attempt to characterize runoff before selecting treatment practices.

Information on this page can be used to help meet water quality targets. Water quality targets are established for various purposes including meeting Clean Water Act (CWA) requirements, meeting local water quality goals or requirements, and meeting non-regulatory targets. CWA requirements include antidegradation, TMDL limits, and NPDES permit requirements. Each of these are described below.

Information: Note that information presented in the Stormwater Manual can be used to meet NPDES permit requirements. This includes information on all BMPs discussed in the Manual unless otherwise noted. Check with MPCA's Stormwater Program for applicability of information not contained in the Manual, including BMPs and BMP credits.

Antidegradation

Water quality standards include an antidegradation policy and implementation method. The water quality standards regulation requires States and Tribes to establish a three-tiered antidegradation program to protect existing water quality and water uses in receiving waters (see [10]).

Compliance with Minimum Control Measure (MCM) 5 of the MS4 permit constitutes compliance with antidegradation requirements. The permit requires no net increase in discharges of volume, total phosphorus (TP) and total suspended solids (TSS) for new development, while a reduction in these are required for redevelopment projects covered under the permit. Practices that infiltrate or capture and reuse stormwater runoff are typically used to meet these permit requirements because they help meet the volume requirements.

Total Maximum Daily Loads (TMDLs)

The 2016 impaired water list includes 358 lakes or reservoirs and 44 river or stream stretches impaired for nutrrient/eutrophication biological indicators. Phosphorus is likely to be the surrogate pollutant for most of these impairments. Other impairments, such as those for dissolved oxygen, may also be associated with excessive TP loads. Click here to link to MPCA's impaired waters website.

The MS4 permit requires permittees to demonstrate progress toward meeting applicable Wasteload Allocations in U.S. EPA-approved TMDLs. General information on meeting TMDL requirements in NPDES permits is found here, while reporting requirements are found here. Below is additional information that may be useful.

Permittees with required reductions in TP loading should consider implementing a treatment train approach.

Stormwater design recommendations to enhance phosphorus removal

Summary of stormwater design recommendations to enhance phosphorus removal.
Link to this table

BMP Design Design recommendations
Infiltration
Filtration (includes practices with an underdrain)
  • Organic filters are a source of soluble phosphorus and should not be used
  • Practices with engineered media are acceptable when the appropriate filter media is used
  • Employ finer-grained media in the filter bed with a small diameter (15 microns), or provide a finer-grained layer at mid-depth in the filter profile
  • The process for pretreatment and/or filtration should extend from 36 to 48 hours, where possible
  • Filters should be oriented to provide maximum solar exposure
  • Wet swales are not recommended because they may export phosphorus
  • Open channels should be designed to promote maximum sediment retention
Stormwater ponds1
  • Pond aeration is encouraged
  • Design wet ponds with a depth no greater than 10 feet to prevent stratification and potential release of phosphorus from bottom sediments
  • Avoid the use of dry or dry extended detention ponds
  • Designers should consider the snowmelt runoff volume and design ponds for seasonal operation
  • Use a surface or mid-depth release from the pond
  • Landscape pond to discourage geese
  • Add shallow benches and wetland areas to enhance the plankton community
  • Pond sediments may be amended to retain phosphorus (e.g. iron, aluminum)
Constructed Stormwater wetlands
  • Pond/ wetland system is the preferred wetland design
  • Use a surface or mid-depth release from the wetland
  • Maximize surface micro-topography
  • Landscape wetland to discourage geese

1The recommendations for constructed ponds are from the original Minnesota Stormwater Manual. MPCA anticipates updating this information in the near future.


References

This page was last edited on 11 February 2023, at 13:56.