TCMA Chloride Management Plan - TCMA Chloride Conditions

TCMA Chloride Conditions

Chloride data across the TCMA was compiled and assessed to support the development of the CMP. As part of the TCMA Chloride Project, the MPCA worked with local partners to develop and implement a chloride monitoring program. The objective of the monitoring program was to better inform an understanding of chloride conditions across the TCMA, including seasonality, trends over time, and the potential for high chloride concentrations in the deepest part of lakes. Seventy-four lakes, 27 streams, and eight storm sewers were monitored as part of this effort from 2010-2013. The Chloride Monitoring Guidance for Lakes and Chloride Monitoring Guidance for Streams and Stormsewers were developed by the MPCA and local experts from the TCMA Chloride MSG and can be found on the MPCA’s TCMA Chloride Project website. The monitoring guidance provides recommendations on sample collection, times of the year to sample, as well as guidance for monitoring high risk waters. In addition to data collected in 2010-2013 following the TCMA Chloride Project monitoring program, chloride data from a host of other sources and timeframes were compiled. The data were collected by several local organizations including the MPCA, the United States Geological Survey (USGS), Capitol Region Watershed District (CRWD), Metropolitan Council Environmental Services (MCES), Minneapolis Park & Recreation Board (MPRB), Minnehaha Creek Watershed District (MCWD), Mississippi Watershed Management Organization (MWMO), Ramsey County Environmental Services, Ramsey-Washington Metro Watershed District (RWMWD), Rice Creek Watershed District, Scott County Watershed Management Organization, and Three Rivers Park District. A large portion of the data were compiled and submitted to the State of Minnesota’s Environmental Quality Information System database (EQuIS). All data collected by Metropolitan Council are available on their Environmental Information Management System (EIMS) database, and data collected by USGS are available on their water-quality data for the Nation database: waterdata.usgs.gov/nwis/qw.

Information: A STREAM, LAKE OR WETLAND IS IMPAIRED BY CHLORIDE IF Two or more samples exceed 230 mg/L within a three-year period; Or, One sample exceeds 860 mg/L.

The impacts of climate change create uncertainty related to winter salt application and chloride levels in TCMA waters in the future. Predictions provided by the United States Global Change Research Program for the TCMA area include warmer winter temperatures by 5 - 6 degrees Fahrenheit, longer freeze-free seasons increasing by 20-30 days, greater winter precipitation, and the likelihood of more frequent extreme events (Kunkel et al. 2013). On the one hand, these predictions of climate change may result in reduced salt use. On the other hand, more frequent snow events, more extreme events, and potentially more frequent ice storms may result in greater needs for deicing roads. Continued monitoring of climate change and chloride concentrations in the TCMA waters, tracking of salt use on all paved surfaces, and an adaptive process will be needed to restore and protect the TCMA waters from chloride impairments with the prospects of a changing climate.

The remainder of this section will present an overview of the assessments conducted based on the available data, including determinations of impairment, time and spatial trends in chloride concentrations, the TMDLs developed for impaired waters, and waters showing a high-risk for future impairment.

Condition Status

This section describes the current status of water resources within the TCMA with respect to applicable chloride criteria. The status of surface waters including lakes, wetlands and streams is presented first. The status of groundwater resources is presented second.

Surface Water

2014 Chloride Assessment Results in the TCMA

The MPCA’s approach to determining whether or not a stream, lake, or wetland is impaired by chloride relies on an assessment of available data. The MPCA conducted an assessment for chloride in the TCMA waterbodies in 2013. Two or more exceedances of the chronic criterion of 230 mg/L within a three-year period are considered an impairment. One exceedance of the acute criterion of 860 mg/L is considered an impairment. The 2013 TCMA chloride assessment resulted in 29 new chloride impairments (6 streams, 19 lakes, and 4 wetlands) added to the 2014 draft impaired waters list, resulting in a total of 39 chloride impairments in the TCMA. Shingle Creek and Nine Mile Creek were previously listed as impaired with completed chloride TMDLs. Approximately 11% of the 340 waterbodies assessed were determined to be impaired. An additional 38 (11%) were classified as high risk and 11% did not have enough data. High risk was defined as a waterbody having one sample in the last 10 years that was within 10% of the chronic criteria (207 mg/L). An interactive map showing assessed, impaired, not impaired, and high risk waters is on the MPCA Chloride Project website (MPCA Chloride Project Website Map of Assessments and Impairments). The assessed lakes, wetlands, and streams are shown on Figure 1. The highest density of impairments is in the heavily urbanized area in Hennepin and Ramsey Counties, though three streams in the outlying suburban areas are also impaired by chloride. The chloride causing impairments in the streams in the outlying areas of the metro is largely effluent from the WWTPs, rather than deicing salt.

It is important to keep in mind that of the over 1,000 lakes, wetlands and streams in the TCMA, less than one-third had chloride data to make an assessment of impairment/attainment of water quality criteria. Also, of those waters with adequate data to make an assessment, only 30% were part of the TCMA Chloride Project monitoring program, which was developed to collect samples at critical times of the year and critical locations. As a result, data used to evaluate water quality conditions in waters not part of the TCMA Chloride Project monitoring program, may not have been representative of critical conditions. Critical times of the year for collecting chloride samples are typically during the winter snowmelt runoff (February through March) and during low flow periods, and critical areas for collecting chloride samples in a lake are near the bottom.

Comparison of Impaired Lakes and Wetlands in the TCMA

The impaired lakes, wetlands, and streams were compared by the concentrations of chloride ranked from highest to lowest concentrations. These rankings are presented in Figure 2 and Figure 3. These figures are not a direct reflection of the 303(d) listing assessment; they are intended to make a relative comparison of the extent of impairment across impaired waters. The values presented in these figures were calculated by identifying the maximum chloride concentration measured in a waterbody on individual sampling days, then averaging all individual sampling day maximums that exceeded the standard of 230 mg/L from 2003-2013. These figures indicate the variability in one waterbody or watershed to the next by the severity of the impairment. These rankings can be used by chloride users to prioritize management activities by area. Since only a portion of the TCMA waters have chloride monitoring data, the rankings can also be used to determine specific areas that are close to impaired and high-risk watersheds for further monitoring and higher levels of management.

Comparison of Impaired Streams in the TCMA.PNG

Groundwater

Chloride concentrations in shallow groundwater are increasing, likely as a result of the application of deicing salt. This correlation is observed in a recent study by the MPCA, The Condition of Minnesota’s Groundwater, 2007-2011, which found that chloride concentrations were higher in wells sampled in urban areas, where salt is more commonly applied in winter months, compared to wells sampled in areas that were undeveloped (Table 2).

Average chloride concentrations in groundwater based on land use
Link to this table

Land Use	Chloride (mg/L)
Residential	45 mg/L
Commercial/Industrial	60 mg/L
Undeveloped	15 mg/L

The median chloride concentration in sand and gravel aquifers in the TCMA was 86 mg/L, compared to a median concentration of 17 mg/L in sand and gravel aquifers outside the TCMA. Twenty-seven percent of sand and gravel monitoring wells in the TCMA had chloride concentrations greater than 250 mg/L, the secondary maximum contaminant level set by the EPA (Figure 4). Very few monitoring wells outside the TCMA (about 1%) had chloride concentrations exceeding 250 mg/L.

Chloride concentrations in ambient groundwater from the sand and gravel aquifersf

Chloride Sources

Chloride enters the TCMA lakes, streams, wetlands, and groundwater from a variety of sources. The relative significance of each source of chloride is dependent on the watershed. For highly developed urban areas, winter maintenance activities are typically the primary source. In less developed areas where point source discharges exist, the municipal wastewater treatment facilities may be the primary source of chloride, which in most cases is due to water softening. A conceptual model diagram of the primary anthropogenic sources is shown in Figure 5. A chloride budget for the TCMA estimated that only 22%-30% of the chloride applied in the TCMA was exported out of the TCMA via streamflow in the Mississippi, Minnesota, and St. Croix Rivers (Stefan et al. 2008). Therefore, 70%-78% of the applied chloride remains in TCMA lakes, wetlands, and groundwater and it may also be stored in soil-water where infiltration is slow. Since chloride is an element and does not breakdown over time, the high percentage retained in the TCMA suggests that chloride will continue to accumulate and eventually make its way to the deep aquifers. This implies that, on average, chloride concentrations in the TCMA waterbodies are increasing with time. If the chloride loading remains steady, the concentrations will level out when equilibrium develops between loadings and transport out of the TCMA. By the same token, if loadings are reduced sufficiently and persistently, the chloride concentrations in the TCMA waterbodies will begin to decrease and will continue to decrease until a new equilibrium is reached. Each of these sources is briefly described below.

Conceptual model of anthropogenic sources of chloride and pathways

Land Use in the TCMA (based on the National Land Cover Database from 2011

As shown in Figure 6, land use in the TCMA is largely urban in the core of Minneapolis and St. Paul with a transition to rural and agricultural moving outward through the suburbs. The primary source of chloride may shift locally depending on land use. Section 2.3 discusses the correlation of road density and chloride concentrations in surface waters.

Winter Maintenance Activities

Winter maintenance activities include snow and ice removal. Application of deicing and anti-icing chemicals, primarily salt, is common. Salt is applied to a variety of surfaces including roads, parking lots, driveways, and sidewalks. Runoff from salt storage facilities is another potential source of salt. The St. Anthony Falls Laboratory at the UMN developed an inventory of salt uses in the TCMA for a Minnesota Department of Transportation (MnDOT) Local Roads Research Board study (Sander et al. 2007). The inventory estimated the total amount of salt used for winter maintenance activities in the TCMA, based on purchasing records, to be 349,000 tons per year. Estimates of use by various entities are shown in Figure 7.

Salt sales data in the United States shows a dramatic increase in the amount of salt being purchased. Figure 8 below from the Salt Institute illustrates this increasing trend. Along with the increased use of salt, increasing levels of chloride in lakes, wetlands, and streams should be expected.

Distribution of NaCl in the TCMA (Figure adapted from Sander et al.PNG

Road Salt Sales Trend in the United States.PNG

Roads

The TCMA is estimated to have over 26,000 lane miles of roadways (Sander et al. 2007). Application rates range from 3 to 35 tons of road salt, per lane mile, per year, based on the salt purchasing records and the number or lane miles of MnDot, counties, and cities in the TCMA (Wenck 2009)

A survey of municipal winter maintenance professionals in the TCMA, done by LimnoTech in 2013, found that typical application rates range from 100 - 600 pounds of salt applied per lane mile per event, which is consistent with previous evaluations of road salt application rates. However, rates can be much higher on hills, near intersections, and other ice problem areas. Higher speed roadways will typically have higher road salt application rates. Some events may require multiple passes of salt application and increase the application rate per event.

=Commercial Parking Lots, Driveways, and Sidewalks

Commercial sources of deicing salt can vary greatly between different watersheds and includes salt applied to parking lots, driveways, and sidewalks on commercial property. The land owner or tenant may conduct winter maintenance activities, or winter maintenance may be contracted with private winter maintenance providers. Commercial sources are likely responsible for 10% and 20% of the total salt applied to paved surfaces in the TCMA (Wenck 2009). The MPCA and Fortin Consulting conducted research to validate and refine assumptions regarding commercial and private salt application rates specific to Minnesota (Fortin 2012a). There is a range of reported application rates, which is to be expected, because rates should vary based on temperature, type of snow event, surface to where material is applied, number of passes over an area during an event, and type of material used. Application rates of salt on parking lots are estimated to range from 0.1 to 1 ton per acre per event, and typically 6.4 tons per acre per year. For sidewalks, the application rate is estimated to range from 8 to 25 pounds per 1,000 square feet per event (0.2 to 0.5 tons per acre per event). More area specific residential and commercial estimates of chloride usage can be determined on a watershed basis by digitizing all of the residential and commercial impervious surfaces and multiplying by the estimated application rates.

Review of available information and additional research included application rates from across the United States’ and Canada’s snowbelt, with an emphasis on Minnesota specific data. It was determined that an average rate of 6.4 tons per acre per event is the appropriate application rate to expect on parking lots. As a percent of the total deicing salt usage, it is estimated that anywhere between 5% and 45% is used for commercial applications (parking lots, sidewalks, residential, private roads). The amount of chloride from commercial sources is variable, and is dependent on the characteristics of the watershed, including the amount of impervious area. Additional estimates of commercial salt use are presented below.

• The Nine Mile Creek Chloride TMDL report, used data on salt purchases from Sander et al. (2007) and Novotny et al. (2008), but weighted the data based on land use. It was determined that the relative contribution for commercial and packaged deicer in the Nine Nile Creek watershed was 38% of the total amount of road salt that is applied (Barr Engineering 2010).
• In the Shingle Creek TMDL, it was estimated that 7.5% of salt application was by commercial/private applicators. This figure was based on the estimates used in Canada. “Cheminfo (1999) estimated that commercial and industrial consumers represented approximately 5 to 10% of the deicing salt market. In quantifying total deicing salt application in Canada, Environment Canada used the midpoint of these data (7.5%) to represent commercial and industrial salt application (Environment Canada 1999).” (Wenck 2006).
• Sander et al. (2007) estimated that the bulk deicing salt applied by commercial snow and ice control companies accounted for 19% of the total salt used in the TCMA, while packaged deicer for home and commercial use was estimated to account for 5% of the total in the TCMA.
• Novotny et al. (2008) used market share amounts from the USGS annual mineral reports and the market share report published annually from the Salt Institute. TCMA amounts were estimated based on national amounts combined with the commercial bulk (19%) and packaged (5%) deicer estimates for a total of 24%.
  • On a national basis, the Salt Institute estimated that 20% of bulk road salt purchases were by non-governmental entities.
  • The USGS estimated 13% of ice control salt is for commercial use.
• A chloride TMDL study in New Hampshire reported a chloride application rate of 5.7 to 6.4 tons per acre per year for parking lots and drives (Sassan and Kahl 2007). Parking lots were 47% of paved surfaces in the watershed and accounted for 36% of the chloride load. The study also estimated that 45% of salt was applied by private applicators.

Private Parking Lots, Driveways, and Sidewalks (residential)

Residential winter maintenance salt use has been estimated from purchasing records. Packaged deicer for home and commercial use is estimated to account for 5% of the total in the TCMA (Sander et al. 2007). See Figure 7.

A Sidewalk Salt Survey was conducted to qualitatively assess the use of sidewalk salt by the general public in the TCMA. The survey was disseminated by local partners including RWMWD, MCWD, and MnDOT. The survey was administered through an on-line Survey Monkey link on the MCWD website (www.minnehahacreek.org) from November 2011 through March 2012. The survey was completed by 606 people online and 148 completed a paper survey. Approximately 47% of the respondents lived in St. Paul or Minneapolis, and other respondents lived in surrounding cities including Woodbury, Richfield, Plymouth, and Maplewood. Although the survey sampled 754 residents, the results represent a small percentage of the TCMA population and are non-random/voluntary; therefore, the survey is not representative of all residents in the TCMA. However, the data provide valuable information on the use of sidewalk salt by TCMA residents.

The majority of residents that responded to the survey used sidewalk salt (57%), particularly on sidewalks and steps. Most people selected products based on performance in colder temperatures and environmental safety. The majority of respondents did not know how much sidewalk salt to use (59%), and if they did know, they determined how much to use based on the instructions on the packaging or used as little as possible. For complete results of the survey see Appendix C.

Municipal and Industrial Treatment Facilities

Municipal wastewater, backwash from municipal WWTPs, and industrial facilities with waste streams may contain chloride. The primary source of chloride in a municipal waste stream comes from water softeners. Many cities do not soften drinking water before it is distributed to residents. Many residents soften the water in their home with personal water softeners. The most common water softening systems use NaCl or potassium chloride (KCl). Salt that contaminates the groundwater can enter the sanitary sewer system through cracks and/or leaks in the pipes and pipe joints. Industrial facilities that discharge to the municipal wastewater collection system can be another source of chloride. Some industries have chloride in their discharge due to the products they produce or chemicals they use (Henningsgaard 2012).

Industrial facilities may discharge directly to surface waters following treatment or may discharge to a sanitary sewer system, which transports the wastewater to a wastewater treatment plant (WWTP) for further treatment prior to discharge to surface water. A range of industrial facilities discharge directly to waters that are already impaired by chloride, these include food processing facilities, manufacturing, pipeline terminals, biofuel facilities, and groundwater treatment systems. Discharges of chloride from municipal and industrial wastewater sources are covered by individual or general permits. Chloride data for wastewater and industrial sources is currently not widely available. However, chloride monitoring is being required for many facilities as permits are re-issued. As part of the TMDL component of this project, several facilities were identified that likely discharge chloride within the impaired watershed. A table listing these facilities and their location is shown in Appendix A-3. There are likely additional facilities with the potential to contain chloride in their discharge; however, since they are not contributing to an impairment they were not evaluated at this time.

Residential Water Softeners

In areas with high hardness in the water supply, like the TCMA (See Figure 9), residential water softeners that use salt are common. Hardness is a measure of the calcium and magnesium carbonate concentration in water. Most water softeners use chloride ions to replace the calcium and magnesium ions. Chloride from this salt is delivered to the environment either through discharge to a septic system or by delivery to a WWTP. Septic systems become more prevalent in the rural areas outside of the TCMA urban core. The chloride that comes from septic systems enters the shallow groundwater or local streams through subsurface flow. Chloride loading from any individual home water softener is dependent on many variables and is specific to the individual homeowner’s water chemistry, water use, hardness preferences, and softener efficiency. Estimates of the amount of salt discharged from residential water softeners in the TCMA are not available at this time. However, where the primary source of household water is hard and it is not softened by municipal water utility, residential water softeners are the primary source of chloride to WWTPs. Figure 10 shows the hardness values of drinking water supply wells for the entire state of Minnesota. The Sand Creek watershed, located in Scott County of the TCMA, is an example where the primary source of chloride to surface waters is from water softening; chloride concentrations in WWTP effluent for three WWTPs located in the watershed average from 521 mg/L to 618 mg/L.

Hardness values of drinking water supply wells in the TCMA

Hardness values of drinking water supply wells in Minnesota.PNG

Natural Background Sources of Chloride

Chloride occurs naturally in soil, rock, and mineral formations. Chloride is naturally present in Minnesota’s groundwater due to the natural weathering of these formations. Glacial deposits from eroded igneous rocks and clay minerals with chloride ions attached are potential sources in the TCMA. Natural background levels of chloride in surface runoff and groundwater vary depending on the geology. The natural background concentration in small streams in the TCMA has been estimated to be 18.7 mg/L (Stefan et al. 2008). A natural background concentration for lakes has not been estimated; however, the natural background load from surface runoff to lakes was assumed to be at a concentration of 18.7 mg/L as well. This background concentration characterizes runoff that is not impacted by current or historical applications of anthropogenic sources of chloride. Concentrations of chloride in precipitation are estimated to be 0.1 mg/L to 0.2 mg/L (Chapra et al. 2009).

Agriculture=

Agricultural crop land may be a small source of chloride to lakes and streams. Fertilizers and biosolids from food processing and publicly owned treatment works contain chloride. The application of fertilizers and biosolids on crop land can result in chlorides being transported to lakes and streams through surface runoff, as well as infiltration into shallow groundwater and subsequent transport to lakes and streams. KCl is the most commonly used fertilizer containing chloride. While not expected to be a significant source of chloride, estimates of the amount of chlorides in land applied fertilizers and biosolids in the TCMA are not available.

An on-going evaluation of agricultural drainage water quality done by North Dakota State University – Department of Agriculture and Biosystems Engineering indicates that chloride concentrations from agricultural drainage can range from 8.6 mg/L to 37.4 mg/L. [The results of this study have not been published].

Other Potential Sources

Sources of chloride to TCMA lakes, wetlands, and streams other than those discussed above exist, but are considered to be small. One such source of chloride is the use of dust suppressants on gravel roads and parking areas. Chloride is a common constituent found at high concentrations in dust suppressants. Landfill leachate has also been shown to contain elevated levels of chloride (Mullaney et al. 2009). The use of aluminum chloride for treatment of lake sediments or ferric chloride for treatment of stormwater are sources of chloride and should be avoided in waters and watersheds with chloride impairments.

Chloride Trends

This section of the CMP presents evaluations of chloride water quality conditions in the TCMA considering:

• Seasonal chloride trends in surface waters
• Long-term chloride trends
• Chloride trends within lakes
• Chloride relationships to watershed characteristics
• Chloride concentrations in stormwater
• Chloride relationships between surface and groundwater

This information is intended to help inform management decisions such as where and when to focus monitoring efforts and where to prioritize implementation activities.

Seasonal Chloride Trends in Surface Waters

Monthly average chloride concentations in Powderhorn Lake.PNG

Chloride data were evaluated for seasonal trends by looking at monthly chloride concentrations. Seasonal trends can help determine the cause of elevated chloride concentrations. Causes can be direct runoff from winter maintenance practices using chloride, groundwater inputs (primarily from infiltrated chloride containing deicers) during low flow, and WWTP inputs.

For the majority of impaired lakes, chloride concentrations were highest January through May. Figure 11 presents an example of the seasonal variability observed in Powderhorn Lake. Powderhorn Lake does not have a natural outlet and has little opportunity to flush chloride from the lake. For streams, chloride concentrations were highest December through April. Lakes tended to show less variation seasonally than streams, as would be expected due to the longer residence time and mixing that occurs in a lake.

Monthly average chloride concentations in Bassett Creek

Monthly average chloride concentations in Battle Creek

There are some streams where chloride concentrations are influenced significantly by sources other than winter maintenance activities, such as WWTPs. These streams tended to show the highest chloride concentrations when flows were low. Low flows generally occur during winter months and dry summer months (July through September) when runoff is low. Sand Creek is an example and is shown in Figure 14. Chloride concentrations in Sand Creek were highest in late summer and winter and lowest in spring and early summer. Limited chloride data from the WWTPs discharging to Sand Creek confirm this as a significant source of chloride. Elm Creek is another stream that exhibits highest chloride concentrations in summer, as shown in Figure 15, but does not have the WWTPs contributing to the chloride concentration, indicating a different source is present that requires further investigation.

Monthly chloride concentrations (average, maximum, and minimum) in Sand Creek

Monthly chloride concentrations (average, maximum, and minimum) in Elm Creek.PNG

Long-Term Chloride Trends

Long-term statistical trend analyses require a long, mostly continuous, monitoring record. Sufficient data were available in EQuIS to conduct long-term statistical trend analysis for 11 of the impaired lakes and 9 of the high risk lakes in the TCMA. Trends were determined using the Season Mann Kendall Trend Test with R Statistical Software and are presented in Table 3. Lakes with a minimum of 10 years of data were analyzed and only samples collected from the surface were used in the analyses. Fourteen lakes showed a significant (p < 0.05) increasing trend in chloride and eight lakes did not have a significant trend. Figure 16 shows an increasing trend in chloride concentration in Gervais Lake. The other lakes in Table 3 showed similar trends.

Long-term chloride trends in lakes in the TCMA
Link to this table

Lake	Period	Percent change/year	Trend Description
Beaver	1984-2014	+2.42%	Increasing
Bennett	1984-2014		No trend
Calhoun	1991-2014	+1.74%	Increasing
Carver	2004-2014		No trend
Como	1984-2014		No trend
Gervais	1983-2014	+3.72%	Increasing
Hiawatha	1994-2014		No trend
Johanna	1984-2014	+3.37%	Increasing
Keller (Main Bay)	1983-2014	+3.85%	Increasing
Kholman	1983-2014	+3.62%	Increasing
Lake of the Isles	1991-2014		No trend
Loring	1995-2014		No trend
McCarron	1985-2014	+2.41%	Increasing
Powderhorn	1994-2014		No trend
Silver	1979-2014	+2.92%	ncreasing
South Long Lake	1984-2014	+3.66%	Increasing
Spring	1995-2014	+4.34%	Increasing
Tanners	2004-2014	+3.63%	Increasing
Valentine	1990-2014	+5.56%	Increasing
Wabasso	1984-2014	+1.92%	Increasing
Wakefield	1984-2014		No trend
Wirth	1994-2014	+2.49%	Increasing

Reasing chloride concentration in surface samples in Gervais Lake from 1983-2014